Effect of precursors on carbon dot functionalization and applications: a review

Abstract

Carbon dots (CDs) are a type of carbon-based nanoparticle (NP) that have risen in popularity due to their unique tuneable physicochemical and optical properties. CDs have received a significant amount of attention in biological based applications due to their low cytotoxicity, stable photoluminescence, and small size. They have demonstrated the ability to retain certain properties from their carbon precursors, enabling NP design via precursor selection. Thus, direct functionalization of a CD can be achieved without the need for post synthesis modification. However, CDs derived from the same class of carbon precursor can also have profoundly variable applications. Indicating that, in conjunction with precursor properties, other functional attributes can be imposed on the CD during the synthesis process to enable cross-cutting applications from a single carbon precursor. Here, we will highlight various CD precursors and the resulting multifunctional CDs, as well as rational design of CDs for specific biological and materials science applications via precursor selection.