Multifractal Analysis of Disperse Polymetallic Systems

IF 1 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Doklady Chemistry Pub Date : 2025-03-19 DOI:10.1134/S0012500825600105
M. E. Kolpakov, A. F. Dresvyannikov, E. A. Ermolaeva
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Abstract

Multifractal analysis is one of the tools for studying complex systems with a self-similar structure, e.g., disperse polymetallic systems. This paper studied the application of multifractal analysis to describe and evaluate the characteristics of disperse polymetallic systems (Fe–Al–Co, Fe–Al–Cr, Fe–Al–Mo) obtained by galvanic substitution. The study resulted in the identification of important aspects, such as the distribution of fractal dimensions, which allows for a deeper understanding of the mechanisms of formation and development of structures in polymetallic systems. The presented results can be useful for the development of new materials and technologies, as well as for improving existing methods of analysis and quality control of polymetallic systems. It was shown that the spectrum of generalized fractal dimensions of Fe–Al–Co is similar to the spectrum of the Sierpinski dodecahedron—an S-shaped descending curve. The calculated generalized fractal dimension is 1.662, which indicates a lower complexity of the structure of the Fe–Al–Co sample compared to the model Sierpinski dodecahedron. A micrograph of a particle of a synthesized dispersed sample of the Fe–Al–Cr system shows an agglomerated structure of micron sizes, which, in turn, is formed from interconnected spherical formations with a size of 50–200 nm. The spectrum of generalized fractal dimensions of Fe–Al–Cr also represents an S-shaped ascending curve. The generalized fractal dimension in this case is 1.881, which is higher than that of the sample of the disperse Fe–Al–Co system. The results obtained showed that the multifractal spectrum and the distribution of fractal dimensions can serve as tools for analyzing the mechanisms of formation and evolution of the structure of polymetallic systems. This opens new opportunities for the development of innovative materials with specified properties and the improvement of existing technologies and quality control of materials.

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分散多金属体系的多重分形分析
多重分形分析是研究具有自相似结构的复杂体系,如分散多金属体系的工具之一。本文研究了用多重分形分析方法描述和评价电取代法制得的分散多金属体系(Fe-Al-Co、Fe-Al-Cr、Fe-Al-Mo)的特性。研究结果确定了重要的方面,如分形维数的分布,这使得人们对多金属体系结构的形成和发展机制有了更深入的了解。所提出的结果可用于新材料和新技术的开发,以及改进现有的多金属体系的分析和质量控制方法。结果表明,Fe-Al-Co的广义分形维数谱与Sierpinski十二面体s型下降曲线谱相似。计算得到的广义分形维数为1.662,表明Fe-Al-Co样品的结构复杂度低于Sierpinski模型十二面体。合成的Fe-Al-Cr体系分散样品的颗粒显微照片显示出微米大小的凝聚结构,而这种结构又是由相互连接的球形结构形成的,尺寸为50-200 nm。Fe-Al-Cr的广义分形维数谱也呈s型上升曲线。该样品的广义分形维数为1.881,高于Fe-Al-Co分散体系样品的广义分形维数。结果表明,多重分形谱和分形维数分布可以作为分析多金属体系结构形成和演化机理的工具。这为开发具有特定性能的创新材料以及改进现有技术和材料质量控制提供了新的机会。
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来源期刊
Doklady Chemistry
Doklady Chemistry 化学-化学综合
CiteScore
1.20
自引率
12.50%
发文量
7
审稿时长
6-12 weeks
期刊介绍: Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.
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