Jason Y. Wang , Flora Fan , Madeline E. Ruos , Leticia Adao Gomes , Mimi Lavin , Thomas J. O'Connor , Steven A. Lopez , Abigail G. Doyle
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引用次数: 0
Abstract
Herein, we describe the discovery and characterization of multiple N-(hetero)aryl, N-benzyl and N-alkyl derivatives of 9-mesityl-3,6-di-tert-butyl-10-phenyl acridinium photocatalyst. The catalytic performances of these catalysts as photo-oxidant or photo-reductant (via in situ generated acridine radical) were compared in three model reactions. We also identified improved catalytic conditions for a previous cyanoarene-catalyzed nucleophilic amination reaction using a synthesized N-cycloheptyl acridinium catalyst (up to 98 % yield).
期刊介绍：
Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.
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