Vladislav V. Komarov, Tatyana V. Mezhenkova, Victor M. Karpov, Yaroslav V. Zonov, Vyacheslav I. Krasnov
{"title":"Formation of polyfluoro-1-ethylfluorenes in the reaction of perfluoropropylbenzene with tetrafluorobenzenes in an SbF5 medium","authors":"Vladislav V. Komarov, Tatyana V. Mezhenkova, Victor M. Karpov, Yaroslav V. Zonov, Vyacheslav I. Krasnov","doi":"10.1016/j.jfluchem.2023.110186","DOIUrl":null,"url":null,"abstract":"<div><p>The interaction of perfluoropropylbenzene with 1,2,3,4-tetrafluorobenzene or 1,2,4,5-tetrafluorobenzene in an SbF<sub>5</sub> medium at r.t. yields corresponding 1-(tetrafluorophenyl)perfluoro-1-phenylpropanes, which undergo cyclization into perfluoro-9-ethylfluorene or 1,2,3,4,5,7,8,9-octafluoro-9-(pentafluoroethyl)fluorene along with 1,2,3,4-tetrahydro-9<em>H</em>-fluorenes under the reaction conditions. The reaction of perfluoropropylbenzene with 1,2,3,5-tetrafluorobenzene under the same conditions leads to the formation of 1-(2,3,4,6-tetrafluorophenyl)perfluoro-1-phenylpropane, which does not give cyclization products at 50–55 °C.</p></div>","PeriodicalId":357,"journal":{"name":"Journal of Fluorine Chemistry","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2023-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fluorine Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S002211392300101X","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The interaction of perfluoropropylbenzene with 1,2,3,4-tetrafluorobenzene or 1,2,4,5-tetrafluorobenzene in an SbF5 medium at r.t. yields corresponding 1-(tetrafluorophenyl)perfluoro-1-phenylpropanes, which undergo cyclization into perfluoro-9-ethylfluorene or 1,2,3,4,5,7,8,9-octafluoro-9-(pentafluoroethyl)fluorene along with 1,2,3,4-tetrahydro-9H-fluorenes under the reaction conditions. The reaction of perfluoropropylbenzene with 1,2,3,5-tetrafluorobenzene under the same conditions leads to the formation of 1-(2,3,4,6-tetrafluorophenyl)perfluoro-1-phenylpropane, which does not give cyclization products at 50–55 °C.
期刊介绍：
The Journal of Fluorine Chemistry contains reviews, original papers and short communications. The journal covers all aspects of pure and applied research on the chemistry as well as on the applications of fluorine, and of compounds or materials where fluorine exercises significant effects. This can include all chemistry research areas (inorganic, organic, organometallic, macromolecular and physical chemistry) but also includes papers on biological/biochemical related aspects of Fluorine chemistry as well as medicinal, agrochemical and pharmacological research. The Journal of Fluorine Chemistry also publishes environmental and industrial papers dealing with aspects of Fluorine chemistry on energy and material sciences. Preparative and physico-chemical investigations as well as theoretical, structural and mechanistic aspects are covered. The Journal, however, does not accept work of purely routine nature.
For reviews and special issues on particular topics of fluorine chemistry or from selected symposia, please contact the Regional Editors for further details.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
