Design and Development of Novel Nanostructured Visible-Light Active Photoelectrodes based on TiO2 Nanorods for Solar Hydrogen Generation

IF 1.204 Q3 Energy Applied Solar Energy Pub Date : 2023-10-08 DOI:10.3103/S0003701X23600339
U. A. Shaislamov, A. S. Esbergenova, K. Mukimov, O. N. Ruzimuradov
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Abstract

Single crystalline rutile TiO2 nanorods were synthesized by using low temperature hydrothermal synthesis method. Activity of the TiO2 nanorods in the visible light range was achieved by introducing low bandgap semiconductor materials, such as CdS, CdSe, and CdS/CdSe and their photoelectrochemical performances were comparatively investigated. Morphological, microstructural and photocatalytic characterization results revealed that TiO2/CdS/CdSe composite photoelectrode demonstrated superior photocatalytic performance compared to others owing to single crystalline TiO2 core component as well as favorable band alignment of the sensitized CdSe/CdSe nanoparticles.

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基于TiO2纳米棒的新型太阳能制氢可见光活性纳米电极的设计与开发
采用低温水热合成法合成了金红石型TiO2纳米棒。通过引入低带隙半导体材料,如CdS、CdSe和CdS/CdSe,实现了TiO2纳米棒在可见光范围内的活性,并对其光电化学性能进行了比较研究。形态、微观结构和光催化表征结果表明,与其他光电极相比,TiO2/CdS/CdSe复合光电极表现出优异的光催化性能,这是由于单晶TiO2核心组分以及敏化的CdSe/CdSe纳米颗粒的良好能带排列。
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来源期刊
Applied Solar Energy
Applied Solar Energy Energy-Renewable Energy, Sustainability and the Environment
CiteScore
2.50
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0.00%
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0
期刊介绍: Applied Solar Energy  is an international peer reviewed journal covers various topics of research and development studies on solar energy conversion and use: photovoltaics, thermophotovoltaics, water heaters, passive solar heating systems, drying of agricultural production, water desalination, solar radiation condensers, operation of Big Solar Oven, combined use of solar energy and traditional energy sources, new semiconductors for solar cells and thermophotovoltaic system photocells, engines for autonomous solar stations.
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