Impact of poly naphthalene sulfonate on the dispersion stability of iron oxide nanoparticles

Q1 Earth and Planetary Sciences Egyptian Journal of Petroleum Pub Date : 2023-03-01 DOI:10.1016/j.ejpe.2023.01.001
Mohamed Fekry , S.H. Shafek , Fathi S. Soliman , Ahmed Bakry
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Abstract

Iron oxide nanoparticles (IOXn) are unstable in aqueous solutions, which prevents their use in various applications. Because of this, it was proposed to treat the IOXn surface by employing a dispersant like sodium poly (naphthalene formaldehyde) sulfonate (PNS). In a single easy process, the (IPNS) were made by covering the IOXn with PNS. The material's structure, morphology, and magnetic properties were identified using XRD, TEM, Zeta potential, FTIR, HR-SEM, and a VSM. Due to its complex molecular structure and high anionic charge density, the polymeric dispersant (PNS) displays various characteristics. PNS successfully modifies the IOXn surface to create excellent colloidal electrostatic stability. At pH = 8, the zeta potential decreased from −13 to –23 mv. After the coating procedure, the crystalline structure changed into an amorphous one. The average particle size was decreased from 138 to 32 nm. In addition, there was a slight reduction in the magnetization saturation (Ms).

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聚萘磺酸盐对氧化铁纳米颗粒分散稳定性的影响
氧化铁纳米颗粒(IOXn)在水溶液中是不稳定的,这阻碍了它们在各种应用中的使用。因此,有人提出采用聚萘甲醛磺酸钠(PNS)等分散剂对IOXn表面进行处理。在一个简单的过程中,用PNS覆盖IOXn制成(IPNS)。通过XRD、TEM、Zeta电位、FTIR、HR-SEM和VSM对材料的结构、形貌和磁性能进行了表征。聚合物分散剂由于其复杂的分子结构和较高的阴离子电荷密度,表现出多种特性。PNS成功地修饰了IOXn表面,创造了优异的胶体静电稳定性。在pH = 8时,zeta电位从- 13 mv下降到-23 mv。涂层后,晶体结构转变为非晶态结构。平均粒径由138 nm减小到32 nm。磁化饱和度(Ms)略有降低。
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来源期刊
Egyptian Journal of Petroleum
Egyptian Journal of Petroleum Earth and Planetary Sciences-Geochemistry and Petrology
CiteScore
7.70
自引率
0.00%
发文量
29
审稿时长
84 days
期刊介绍: Egyptian Journal of Petroleum is addressed to the fields of crude oil, natural gas, energy and related subjects. Its objective is to serve as a forum for research and development covering the following areas: • Sedimentation and petroleum exploration. • Production. • Analysis and testing. • Chemistry and technology of petroleum and natural gas. • Refining and processing. • Catalysis. • Applications and petrochemicals. It also publishes original research papers and reviews in areas relating to synthetic fuels and lubricants - pollution - corrosion - alternate sources of energy - gasification, liquefaction and geology of coal - tar sands and oil shale - biomass as a source of renewable energy. To meet with these requirements the Egyptian Journal of Petroleum welcomes manuscripts and review papers reporting on the state-of-the-art in the aforementioned topics. The Egyptian Journal of Petroleum is also willing to publish the proceedings of petroleum and energy related conferences in a single volume form.
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