Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene and -allylbenzene; evidence for novel carbon–carbon double and triple bond cleavage and alkyne insertion reactions
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引用次数: 15
Abstract
Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene or -allylbenzene leads to either novel reorganisation reactions involving cleavage of carbon–carbon double and triple bonds, or unusual insertion reactions by PhC2Ph into carbon–hydrogen bonds.
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