Study of Interaction Platinum Salts (Ii) and Palladium (Ii) on the Biologically Active Ligand

A. N. Azizova, D. Tagiyev, O. M. Gyulalov, Kh.I. Hasanov
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引用次数: 0

Abstract

Studied complexing ability of platinum (II) and palladium (II) with a time of personal grayoxygen and sulfur-containing ligands donor nitrogens in different taniyah. A combination of functional groups. It is found that the complexation unimportant role nature of the starting metal salts, the pH of the medium, the nature of the solvent and the ratio of reactants. Determine the actual denticity tiodiuksusnoy, tiodipro propionic acid, mercaptoethanol, and bis -- hydroxyethyl sulfide. Discovered that a molecule entering the reaction of cysteamine origin walks splitting S–S communication and the resulting deproto-bined mercamine enter into complexation. In nonaqueous medium splitting S–S communication occurs.
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铂盐(Ii)与钯(Ii)在生物活性配体上相互作用的研究
研究了铂(II)和钯(II)在不同温度下随个人灰氧和含硫配体给氮时间的络合能力。官能团的组合。结果表明,初始金属盐的性质、介质的pH、溶剂的性质和反应物的配比对络合反应的影响不大。测定实际密度碘二氢磺酸、碘二丙酸、巯基乙醇和双--羟乙基硫醚。发现进入半胱胺源反应的分子走分裂S-S通讯,产生的去原结合的自胺进入络合。在非水介质中发生分裂S-S通信。
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