DETERMINATION OF NECESSARY CONDITIONS FOR EFFICIENT PURIFICATION OF DRINKING WATER WITH HIGH CHLOROFORM CONTENT BY PLASMA TREATMENT IN AEROSOL

Yu.L. Zabulonov, D. Charny, L. Odukalec, D. Yaroshchuk, A. Puhach, O. Arkhypenko, N. Chernova
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引用次数: 1

Abstract

Sustainable development of any country is possible only if the stable supply of its population with drinking water in accordance with their needs, quantity and regulatory quality. This issue is extremely relevant for Ukraine as a low-water state, especially with the further negative impact of climatic and anthropogenic factors on the quality of source water. This is especially true of surface water sources in general and the Dnieper cascade of reservoirs in particular. The regulation of the Dnieper River, global warming and the increase in anthropogenic pressure in the form of a significant (at times) increase in polyphosphates and nitrogen compounds in the effluents entering the Dnieper River provokes catastrophic cyanide growth for four to five months a year. Outdated water treatment technologies are unable to combat this factor and use the only possible technological method for them to combat high organic matter of any genesis – increase the dose of chlorine and coagulants. This usually does not improve the quality of water purification, but leads to the sustainable formation of organochlorine compounds in the process of water purification and transportation. Chloroform is a constant marker of trihalogen methanes and its concentration is determined by water supply laboratories. Accordingly, we investigated the possibilities of oxidation of chloroform by means of complex oxides formed by corona discharge in a water-air medium in the mixing chamber of the ejector. The influence of medium pH on the process of chloroform destruction was studied. It has been experimentally established that even a weakly acidic environment does not allow the efficient oxidation of chloroform and leads to its recombination and even increases its concentration. At the same time, in an alkaline environment, the oxidation process is intense and with lower energy consumption.
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气溶胶等离子体处理高氯仿饮用水有效净化条件的测定
任何国家的可持续发展,只有根据其人口的需要、数量和规范的质量稳定地供应饮用水才有可能。这个问题与乌克兰作为一个低水国家极为相关,特别是在气候和人为因素对水源质量产生进一步负面影响的情况下。一般地表水的水源尤其如此,第聂伯河的水库梯级尤其如此。第聂伯河的治理、全球变暖以及以进入第聂伯河的污水中多磷酸盐和氮化合物(有时)显著增加的形式出现的人为压力的增加,每年有四到五个月引起灾难性的氰化物增长。过时的水处理技术无法对抗这一因素,只能使用唯一可行的技术方法来对抗任何形式的高有机物——增加氯和混凝剂的剂量。这通常不会提高水的净化质量,反而会导致水在净化和运输过程中持续形成有机氯化合物。氯仿是三卤甲烷的恒定标记物,其浓度由供水实验室测定。因此,我们研究了在喷射器的混合室中,通过电晕放电在水-空气介质中形成的复合氧化物氧化氯仿的可能性。研究了培养基pH对氯仿破坏过程的影响。实验证明,即使是弱酸性环境也不能使氯仿有效氧化,导致其重组,甚至浓度增加。同时,在碱性环境下,氧化过程剧烈,能耗较低。
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