Preparación y caracterización de carbón activado a partir de torta de higuerilla

TecnoLogicas Pub Date : 2014-01-15 DOI:10.22430/22565337.207
Viviana M. Ospina-Guarín, Robison Buitrago-Sierra, Diana P. López-López
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引用次数: 9

Abstract

Biomass residues have been used to produce activated carbons. On this process, the activation method and the raw composition determine the properties as porosity and surface area of the charcoal. After the extraction of castor oil, there is a solid byproduct (cake) of low added value, which was used in the production of activated carbon to add value to this waste. For this purpose two traditional methods were used, first, physical activation using as activating agents steam, CO2 and mixture of both, and additionally chemical activation using K2CO3 as the activating agent. Some activated carbons were characterized using N2 adsorption isotherms, BET surface areas varied between 255.98 (m2/g) and 1218.43 (m2/g). By SEM and EDS analysis was possible to observe that materials obtained by the two types of activation are principally amorphous and morphological characteristics of the carbon obtained by physical activation are very different from those obtained by chemical activation. Finally, through impregnation of inorganic phases of Ni and Mo was revealed that the high dispersion characteristics, these carbonaceous materials will have potential to be used as catalyst support.
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higuerilla蛋糕活性炭的制备与表征
生物质残渣已被用于生产活性炭。在这个过程中,活化方法和原料组成决定了木炭的孔隙率和表面积。蓖麻油提取后产生的固体副产物(饼)附加值低,将其用于生产活性炭,对该废弃物进行附加值处理。为此,采用了两种传统的方法,一是用蒸汽、CO2及其混合物作为活化剂进行物理活化,二是用K2CO3作为活化剂进行化学活化。用N2吸附等温线对部分活性炭进行表征,其BET比表面积在255.98 (m2/g) ~ 1218.43 (m2/g)之间变化。通过SEM和EDS分析可以观察到,两种活化方式得到的材料主要是无定形的,并且物理活化得到的碳的形态特征与化学活化得到的碳有很大的不同。最后,通过对Ni和Mo无机相的浸渍揭示了它们的高分散特性,这些碳质材料将有潜力用作催化剂载体。
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发文量
30
审稿时长
28 weeks
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