The research of new induced crystallization nuclear in water softening

Chen Yue-fang, Yu Lu-lu, Shi Yan-qing, Z. Qiang, Xiong Xin-xiang, Guo Kun
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Abstract

Based on the determined metastable region by static beaker tests, this paper studied cation exchange resin in the treatment of recycling cooling water softening, compared to macroporous porous polymer materials resin white balls, cation exchange resins could be obtained as efficient induced crystallization of nuclear, and effluent achieved the circulating cooling water recharge water quality standard. The best experimental conditions for ion-exchange resin was: pH value for 9.24, the amount of Na2CO3 (concentration 0.05mol/L)for 5.0 ml/L, the amount of resin for 40 g/L, mixing time for 20min, and mixing intensity for 200r/min. Ca2+ removal rate reached 94.8% and 94.8%, and effluent's calcium concentration were 0.52mmol/L. And average moisture content of crystalline product was 20.17%, the calcium ions in the carrier's average crystallization of 27.58mg/g.
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水软化中新型诱导结晶核的研究
在静态烧杯试验确定亚稳区域的基础上,研究了阳离子交换树脂在处理循环水软化中的作用,与大孔多孔高分子材料树脂白球相比,阳离子交换树脂可获得高效的诱导结晶核,出水达到循环水回灌水质标准。离子交换树脂的最佳实验条件为:pH值为9.24,Na2CO3(浓度0.05mol/L)用量为5.0 ml/L,树脂用量为40 g/L,搅拌时间为20min,搅拌强度为200r/min。Ca2+去除率分别为94.8%和94.8%,出水钙浓度为0.52mmol/L。结晶产物的平均含水量为20.17%,载体中钙离子的平均结晶量为27.58mg/g。
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