Study the effects of P2O5 mineralization additives on cement clinker quality at low calcination temperature 1300oC and 1400oC

Dung Ngoc Ta, Quang Van Le, C. D. Huynh, Mai Thanh Pham
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Abstract

In this study, the cement clinker was mixed with P2O5 mineralization additives with the rate of 1.0% and 2.0% (compared to the content of cement clinker without P2O5 mineralization additives which was called the control sample) and then this mixture was calcined at temperatures of 1300oC and 1400oC by gas furnace. The mechanical properties of the prepared cement samples were determined: density and free lime content of clinker; normal consistency and setting time of cement paste; soundness and compressive strength of hardened cement paste. The results showed that, the cement samples mixed with P2O5 mineralization additives had free lime content (1.36-1.91%) which was lower than the control sample (1.39-2.34%). The setting time significantly reduced compared with that of the control sample. The soundness of cement samples mixed with P2O5 reache 0.55-1.2 mm in accordance with TCVN 4031:1985 and it was smaller than that of the control sample. The compressive strength of hardened cement paste sample which mixed with P2O5 of 1.0% (at the age of 28 days) reached 25.23 N/mm2 at 1300oC (the control sample reached 24.32 N/mm2) and reached 28.6 N/mm2 at 1400oC (the control sample reached 27.00 N/mm2). The study showed that, The using of P2O5 mineralization additives with appropriate content will bring to the improved quality of the cement clinker.
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研究了P2O5矿化助剂在1300℃和1400℃低温煅烧条件下对水泥熟料质量的影响
在本研究中,将水泥熟料分别以1.0%和2.0%的比例加入P2O5矿化助剂(对照样品为未加入P2O5矿化助剂的水泥熟料),然后在1300℃和1400℃的温度下进行煤气炉煅烧。测定了所制水泥试样的力学性能:熟料密度和游离石灰含量;水泥浆体正常稠度及凝结时间;硬化水泥浆体的稳定性和抗压强度。结果表明:掺加P2O5矿化剂的水泥样品游离石灰含量(1.36 ~ 1.91%)低于对照样品(1.39 ~ 2.34%);与对照样品相比,凝固时间明显缩短。按照TCVN 4031:1985的要求,掺P2O5水泥试样的实度为0.55 ~ 1.2 mm,比对照试样的实度小。当P2O5掺量为1.0%(龄期28天)时,硬化水泥浆体试样的抗压强度在1300oC时达到25.23 N/mm2(对照试样为24.32 N/mm2),在1400oC时达到28.6 N/mm2(对照试样为27.00 N/mm2)。研究表明,掺加适量的P2O5矿化助剂可以提高水泥熟料的质量。
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