Evaluation of the efficiency of polyacrylamide and poly(MMA-HEMA) for the consolidation of vegetable-tanned leather artifacts

G. Abdel-Maksoud, A. Abdallah, R. Youssef, Doha Elsayed, Nesreen Labib, Wael S Mohamed, Medhat A Ibrahim
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引用次数: 1

Abstract

Purpose This study aims to evaluate the efficiency of using some polymers at different concentrations in the consolidation of vegetable-tanned leather artifacts. Design/methodology/approach New vegetable-tanned leather samples were prepared. The consolidants used were polyacrylamide (PAM) and polymethyl methacrylate/hydroxyethyl methacrylate (MMA-HEMA). Accelerated heat aging was applied to the untreated and treated samples. Analytical techniques used were Fourier transform infrared spectroscopy (FTIR), digital microscope, scanning electron microscope (SEM), change of color and mechanical properties. Findings The characteristic FTIR bands showed the effect of accelerated heat aging on the molecular structure of the studied samples, but treated and aged treated samples used were better than aged untreated samples. Microscopic investigations (digital and SEM), and mechanical properties proved that 2% was the best concentration for polymers used. The change in the total color difference of the treated and aged treated samples was limited. Originality/value This study presents the important results obtained from PAM and poly(MMA-HEMA) used for the consolidation of vegetable-tanned leather artifacts. The best results of the studied polymers can be applied directly to protect historical vegetable-tanned leathers.
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聚丙烯酰胺和聚(MMA-HEMA)对植物鞣革制品固结效果的评价
目的评价不同浓度聚合物在植物鞣革制品固结中的效果。设计/方法/方法制备了新的植物鞣革样品。所使用的固结剂是聚丙烯酰胺(PAM)和聚甲基丙烯酸甲酯/甲基丙烯酸羟乙酯(MMA-HEMA)。对未处理和处理过的样品进行加速热时效处理。分析技术包括傅里叶变换红外光谱(FTIR)、数码显微镜、扫描电镜(SEM)、颜色变化和力学性能。发现特征红外光谱显示加速热时效对研究样品分子结构的影响,但处理和时效处理的样品比未处理的样品效果更好。微观研究(数字和扫描电镜)和力学性能证明,2%是聚合物使用的最佳浓度。处理后和时效处理后样品的总色差变化有限。原创性/价值本研究介绍了PAM和poly(MMA-HEMA)用于植物鞣革制品固结的重要结果。所研究的聚合物的最佳效果可以直接应用于保护历史悠久的植物鞣革。
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