Synthesis, Characterization and Structure of Copper(II) complex involving Chloride and Tridentae NNS coordinate Schiff base ligand

Sujit B. Kumar
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Abstract

Mononuclear copper(II) complex [CuLCl2] where L = (2-methylsulfanyl-phenyl)-(phenyl-pyridin-2-yl-methylene)amine, a tridentate NNS donor Schiff base ligand has been synthesized and characterized by microanalysis, IR, UV-Visible spectra and magnetic studies. Crystal structure of the complex has been solved by single crystal X-ray diffraction studies and shows the complex has distorted trigonal bipyramidal geometry.
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氯-三齿NNS配位席夫碱铜配合物的合成、表征及结构
合成了单核铜(II)配合物[CuLCl2],其中L =(2-甲基磺胺基苯基)-(苯基吡啶-2-基亚甲基)胺,是一种三齿状NNS供体席夫碱配体,并通过微量分析、红外光谱、紫外可见光谱和磁性研究对其进行了表征。通过单晶x射线衍射分析,确定了配合物的晶体结构,表明配合物具有扭曲的三角双锥体几何结构。
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