Modelling the molecular weight distribution in terpolymerization systems with donor–acceptor complexes

P. Rivero , E. Etchechury
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引用次数: 8

Abstract

In this work we present, for the first time, a mathematical development of the moments of the molecular weight distribution in terpolymerization systems where donor–acceptor complexes are formed and the propagating reactions are carried out according to the complex participation model. The resulting set of equations is applied to the system formed by vinyl chloride (VC), vinyl acetate (VAc) and maleic anhydride (MA), in order to show the use of the equations and the type of information that might be obtained from them.

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具有供体-受体配合物的三元聚合体系中分子量分布的建模
在这项工作中,我们首次提出了三元聚合体系中分子量分布矩的数学发展,在三元聚合体系中,供体-受体络合物形成,并根据络合物参与模型进行传播反应。将所得的方程组应用于氯乙烯(VC)、醋酸乙烯(VAc)和马来酸酐(MA)组成的体系,以说明方程组的用途和从中可能得到的信息类型。
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