Intermolecular Interaction between Polymer Monolayers and Poly(ethylene glycol) Monostearates at Air/Water Interface

Won‐Ki Lee, H. Nakahara, Hyuntaek Lim, W. Cho, C. Ha
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引用次数: 1

Abstract

Abstract Intermolecular interaction between PEG monostearate with two ethylene glycol units (N=2) and several polymer monolayers at air/water interface was investigated. For polymer monolayers, poly(methyl methacrylate) (PMMA) and poly(isopropenyl acetate) (PIPA) were spread on the distilled water. It was observed that the positive or negative deviation behavior between the mean surface area and the composition of the mixed monolayers in the condensed state is in good agreement with the miscibility behavior of the blends of the component polymers in the bulk state.
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聚合物单层膜与聚乙二醇单硬脂酸酯在空气/水界面的分子间相互作用
摘要:研究了具有两个乙二醇单元(N=2)的聚乙二醇单硬脂酸酯与若干聚合物单层在空气/水界面的分子间相互作用。对于聚合物单层,将聚甲基丙烯酸甲酯(PMMA)和聚醋酸异丙酯(PIPA)涂在蒸馏水上。在凝聚态下,混合单层膜的平均表面积与组成之间的正或负偏差行为与组分聚合物在体态下的共混行为很好地吻合。
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