{"title":"Polyhydroxamic acids: synthesis, ion exchange separation and atomic absorption spectrophotometric determination of divalent metal ions","authors":"Y.K. Agrawal, K.V. Rao","doi":"10.1016/0923-1137(95)00022-B","DOIUrl":null,"url":null,"abstract":"<div><p>The preparation and properties of 8 <em>N</em>-phenylsubstituted polyacrylohydroxamic acids as ion exchange resins are described. These were synthesized by the reaction of polyacryloyl chloride with <em>N</em>-aryl hydroxylamines in etherial medium. The chelating properties of the resins were determined and compared with each other. The extraction of divalent metal ions as a function of pH and kinetics of their sorption were studied. The chromatographic separation of metal ions from the mixtures is also described.</p></div>","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"25 1","pages":"Pages 79-87"},"PeriodicalIF":0.0000,"publicationDate":"1995-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-1137(95)00022-B","citationCount":"11","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactive Polymers","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/092311379500022B","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 11
Abstract
The preparation and properties of 8 N-phenylsubstituted polyacrylohydroxamic acids as ion exchange resins are described. These were synthesized by the reaction of polyacryloyl chloride with N-aryl hydroxylamines in etherial medium. The chelating properties of the resins were determined and compared with each other. The extraction of divalent metal ions as a function of pH and kinetics of their sorption were studied. The chromatographic separation of metal ions from the mixtures is also described.