Effect of Zinc (Zn) -Doped on the Structural, Optical and Electrical Properties of (Cdo)1-Xznx Films Prepared by Pulsed Laser Deposition Technique

H. Abbas, K. Aadim, A. H. Khidhir
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Abstract

Pure cadmium oxide films (CdO) and doped with zinc were prepared at different atomic ratios using a pulsed laser deposition technique using an ND-YAG laser from the targets of the pressed powder capsules. X-ray diffraction measurements showed a cubic-shaped of CdO structure. Another phase appeared, especially in high percentages of zinc, corresponding to the hexagonal structure of zinc. The degree of crystallinity, as well as the crystal size, increased with the increase of the zinc ratio for the used targets. The atomic force microscopy measurements showed that increasing the dopant percentage leads to an increase in the size of the nanoparticles, the particle size distribution was irregular and wide, in addition, to increase the surface roughness of the nanoparticles. An increase in the zinc ratio also led to a decrease in the energy gap. While the Hall effect measuring showed an increase in the concentration of charge carriers and a decrease in their mobility with increasing the doping ratio.
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掺杂锌对脉冲激光沉积(Cdo)1-Xznx薄膜结构、光学和电学性能的影响
采用脉冲激光沉积技术,利用ND-YAG激光从压制粉末胶囊的靶材上制备了不同原子比掺杂锌的纯氧化镉薄膜(CdO)。x射线衍射测量显示为立方形状的CdO结构。另一相出现,特别是在锌含量高的情况下,与锌的六边形结构相对应。所用靶材的结晶度和晶粒尺寸随锌比的增加而增加。原子力显微镜测量结果表明,随着掺杂量的增加,纳米颗粒的尺寸增大,粒径分布不规则且较宽,同时纳米颗粒的表面粗糙度增大。锌比的增加也会导致能隙的减小。霍尔效应测量表明,随着掺杂比的增加,载流子浓度增加,迁移率降低。
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