The efficiency of magnetic TiO2 anatase loaded by graphen quantum dots for photocatalytic degradation of imipramine from aquatic media

R. Hatefi, Habibollh Younesi, Ali Mashinchian-Moradi, S. Nojavan
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Abstract

The efficiency of magnetic TiO 2 anatase loaded by graphen quantum dots for photocatalytic degradation of imipramine from aquatic media. Environmental Sciences. 20(1): 1-20. the of was the type IV and hysteresis loop of types due to mesoporous structure. FESEM images determined the almost spherical morphology of as-synthesized photocatalyst and homogenous distribution of TiO 2 nanoparticles on the magnetite surface that was utilized without any changes in morphology but particle size changing after loading TiO 2 on the magnetite particles. HRTEM results confirmed the spherical shape with less than 50 nm diameter and the lattice spacing related to anatase (TiO 2 ) and GQDs. Also, the photocatalytic efficiency of the as-synthesized nanocomposite was for achieving the maximum removal of related to different best yield 90% experimental and in under the optimum condition of ≈3, ≈40 for the dominant mechanism of imipramine degradation was oxidative decomposition via the photogenerated holes and followed by the first-order models under the UVA light irradiation. Therefore, results proved as-prepared photocatalyst Fe 3 O 4 /TiO 2 /GQDs could be developed for treatment of persistence organic pollutants in industrial wastewater under optimized conditions.
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石墨烯量子点负载磁性TiO2锐钛矿光催化降解水中丙咪嗪的效率
石墨烯量子点负载磁性二氧化钛锐钛矿光催化降解水中丙咪嗪的效率。环境科学,20(1):1-20。由于介孔结构,其滞回线为IV型,滞回线为型。FESEM图像显示,合成的光催化剂形貌接近球形,tio2纳米颗粒在磁铁矿表面分布均匀,在磁铁矿颗粒上加载tio2后,表面形貌没有变化,但颗粒大小发生了变化。HRTEM结果证实该材料为直径小于50 nm的球形材料,其晶格间距与锐钛矿(tio2)和GQDs有关。实验结果表明,所合成的纳米复合材料的光催化效率最高可达90%,且在≈3、≈40的最佳条件下,丙咪嗪降解的主要机制是通过光生成孔进行氧化分解,其次是UVA光照射下的一阶模型。因此,在优化的条件下,制备的光催化剂fe3o4 / tio2 /GQDs可用于处理工业废水中的持久性有机污染物。
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