CHAPTER 8. Noncovalent Interactions in Hydrogenation and Hydroformylation

Vijay S. Koshti, Samir H. Chikkali
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Abstract

This chapter summarizes the fundamentals of hydrogenation and hydroformylation reactions. An overview of state-of-the-art developments is presented to set the context. Subsequently, the significance of noncovalent interactions in these reactions is discussed in detail. Hydrogen bonding has been one of the leading noncovalent interactions that has been very frequently used in catalysis, including hydrogenation and hydroformylation reactions. Recent examples from the literature are presented to illustrate the role of hydrogen bonding in hydrogenation and hydroformylation. The impact of hydrogen bonding on catalyst development through self-assembly and the role of hydrogen bonding in directing a substrate to achieve high enantiomeric excess are discussed.
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第八章。氢化和氢甲酰化中的非共价相互作用
本章总结了氢化和氢甲酰化反应的基本原理。最先进的发展概况提出设置背景。随后,详细讨论了非共价相互作用在这些反应中的意义。氢键是一种主要的非共价相互作用,经常用于催化反应,包括氢化反应和氢甲酰化反应。最近的例子从文献提出,以说明氢键在氢化和氢甲酰化的作用。讨论了氢键通过自组装对催化剂发展的影响,以及氢键在指导衬底实现高对映体过剩中的作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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