Aluminum-rich zeolite beta

F. Vaudry, F. Di Renzo, P. Espiau, F. Fajula, Ph. Schulz
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引用次数: 45

Abstract

Hydrothermal synthesis of zeolite beta with an aluminum content as high as 8 atoms per unit cell has been performed in sodium-tetraethylammonium systems. Low alkalinity is required to avoid the formation of denser phases. Sodium cations are needed for charge balance beyond 6 Al/unit cell. The concentration of lattice defects in the solids richest in aluminum provides information about the templating effect of tetraethylammonium in this system.

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富铝沸石
在钠-四乙基铵体系中,水热合成了铝含量高达8个原子/晶胞的沸石。为避免形成致密相,需要低碱度。超过6铝/单元电池的电荷平衡需要钠离子。在铝中含量最丰富的固体中,晶格缺陷的浓度提供了四乙基铵在该体系中模板效应的信息。
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Metal-organic Frameworks for Catalysis 19th International Zeolite Conference(IZC’19)参加報告 19th International Zeolite Conference(IZC’19)参加報告 実験化学,計算機化学,データサイエンスの融合による設計的ゼオライト合成 古典的なASFモデルを打破するジェット燃料直接合成用Co/Ymeso-La触媒
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