{"title":"Suppression of sulfur trioxide formation in a monolithic catalytic converter for cars due to oscillating reaction conditions","authors":"P. Olsson, N. Schoeoen","doi":"10.1021/I200033A031","DOIUrl":null,"url":null,"abstract":"The net formation of sulfur trioxide in the presence of an excess of carbon monoxide with respect to sulfur dioxide was studied under different reaction conditions in a single element of a commercial monolithic Pt, Rh converter. Conditions giving rise to self-oscillations were found to result in a complete oxidation of carbon monoxide and in only a 10% net conversion of sulfur dioxide.","PeriodicalId":13537,"journal":{"name":"Industrial & Engineering Chemistry Process Design and Development","volume":"27 1","pages":"528-531"},"PeriodicalIF":0.0000,"publicationDate":"1986-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial & Engineering Chemistry Process Design and Development","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1021/I200033A031","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
The net formation of sulfur trioxide in the presence of an excess of carbon monoxide with respect to sulfur dioxide was studied under different reaction conditions in a single element of a commercial monolithic Pt, Rh converter. Conditions giving rise to self-oscillations were found to result in a complete oxidation of carbon monoxide and in only a 10% net conversion of sulfur dioxide.