PHOTO-DEGRADATION OF 5 – FLUOROURACIL. COMPARATIVE STUDY ON THE EFFICIENCIES OF UV/H2O2, UV/TIO2, UV/H2O2/TIO2 PROCESSES

M. Constantin, L. Constantin, Ines Nițoi, I. Cristea, Ellea Boulac
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Abstract

Degradation experiments on 5-Fluorouracil synthetic solutions were performed using three types of advanced oxidation systems: UV/H2O2, UV/TiO2 and UV/H2O2/TiO2. Optimum parameters for all three systems were established and 5-Fluorouracil degradation efficiencies were calculated, for all systems being more than 97%. The results showed that the combined UV/H2O2/TiO2 system is offering shortest irradiation time, the possibility to recover and reuse the photo catalyst as well as the possibility to use solar radiation. Obtained results proved also that advanced oxidation processes represent a viable option for degradation of hazardous pollutants that cannot be removed properly via conventional wastewater treatment processes.
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5 -氟尿嘧啶的光降解。uv / h2o2、uv / tio2、uv / h2o2 / tio2工艺效率的比较研究
采用UV/H2O2、UV/TiO2和UV/H2O2/TiO2三种高级氧化体系对5-氟尿嘧啶合成溶液进行降解实验。建立了三种体系的最佳参数,并计算了5-氟尿嘧啶的降解效率,所有体系的降解效率都大于97%。结果表明,UV/H2O2/TiO2复合体系具有最短的辐照时间、光催化剂回收再利用的可能性以及利用太阳辐射的可能性。所获得的结果也证明,高级氧化工艺是一种可行的选择,可以降解传统废水处理工艺无法正确去除的有害污染物。
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