{"title":"Synthesis, Magnetic and Spectral Studies on Copper(II) Complexes with Bidentate Thiosemicarbazones","authors":"S. Chandra, U. Kumar","doi":"10.1081/SIM-200026270","DOIUrl":null,"url":null,"abstract":"Abstract The synthesis and spectral characterization of new copper(II) complexes of the composition CuL2X2 [where L = 2‐methylcyclohexanone thiosemicarbazone (L1) and 4 N‐methyl thiosemi‐carbazone (L2) and X = Cl, NO3, and 0.5SO4] are reported. All the complexes have been characterized by IR, electronic, EPR, and mass spectral studies, magnetic moments, and conductivity measurements. A tetragonal geometry has been assigned to all the complexes except the sulfato complexes which were found to have five coordinated square‐pyramidal geometry.","PeriodicalId":22160,"journal":{"name":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","volume":"56 1","pages":"1417 - 1430"},"PeriodicalIF":0.0000,"publicationDate":"2004-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/SIM-200026270","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
Abstract
Abstract The synthesis and spectral characterization of new copper(II) complexes of the composition CuL2X2 [where L = 2‐methylcyclohexanone thiosemicarbazone (L1) and 4 N‐methyl thiosemi‐carbazone (L2) and X = Cl, NO3, and 0.5SO4] are reported. All the complexes have been characterized by IR, electronic, EPR, and mass spectral studies, magnetic moments, and conductivity measurements. A tetragonal geometry has been assigned to all the complexes except the sulfato complexes which were found to have five coordinated square‐pyramidal geometry.
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