Study on the Interaction between Depressants Zinc Sulfate and Xanthate on the Flotation of Sphalerite

Minkyu Kim, Kwang-Seok You
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Abstract

In this study, the depression behavior of zinc sulfate on the sphalerite with the addition of potassium butyl xanthate was investigated to clear the relationship between zinc sulfate and xanthate in depression of sphalerite. As a result of the experiment, it was confirmed that the depress effect of zinc sulfate on the sphalerite declined with the increase of its addition amount. From the results of SEM-EDS and FT-IR analysis, it was found out that the amorphous precipitate of metal xanthate (Zn-BX) was formed in sphalerite concentrate, when the solubility product of [Zn]·[BX] in the pulp solution exceeded 3.71×10, which is the solubility of Zn-butyl xanthate. It is considered that the Zn-butyl xanthate had a negative effect on the depression of sphalerite.
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抑制剂硫酸锌与黄药在闪锌矿浮选中的相互作用研究
本研究考察了添加丁基黄药钾后硫酸锌对闪锌矿的抑制行为,以明确硫酸锌与黄药对闪锌矿抑制的关系。实验结果证实,硫酸锌对闪锌矿的抑制作用随着硫酸锌添加量的增加而减弱。SEM-EDS和FT-IR分析结果表明,当[Zn]·[BX]在矿浆溶液中的溶解度积超过3.71×10时,闪锌矿精矿中形成金属黄药(Zn-BX)的无定形沉淀,这就是Zn-丁基黄药的溶解度。认为丁基黄药锌对闪锌矿有抑制作用。
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