FEATURES OF THE INFLUENCE OF RECIRCULATION OF COMBUSTION PRODUCTS ON THE FORMATION OF NITROGEN OXIDES IN BOILERS DURING BURNING NATURAL GAS

I. Sigal, A. Smikhula, O. Sigal, O. Marasin, E. S. Kernazhytska
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引用次数: 6

Abstract

During the combustion of natural gas and the supply of exhaust gases recirculation like a ballast was shown. It is necessary to take into account that they contain nitrogen oxides, mainly in the form of NO, which does not decompose in the combustion zone, but is added to nitrogen oxides that has been produced during burning of fuel. The combustion products are affordable, but not ideal ballast. As on the one side, they reduce the maximum temperature in the combustion zone and the concentration of reagents, i.e. reduces the formation of «thermal» NOx, on the other side, they add to the combustion zone an additional amount of nitric oxide, which is summed up with that has been formed during burning in the combustion chamber and also reducing the efficiency of the method. When the maximum temperature in the combustion zone is the highest and the entire volume of fuel and ballast before to the combustion is best mixed during recirculation of exhaust gases, their effect on the formation of nitrogen oxides is the highest. The most effective ballast that reduces the formation of NO during combustion is carbon dioxide, provided it is well pre-molecularly mixed with natural gas before to the combustiontion zone. Bibl. 16, Tab. 4, Fig. 2.
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燃烧产物再循环对锅炉燃烧天然气过程中氮氧化物形成影响的特征
在天然气燃烧过程中,废气像镇流器一样循环供给。要考虑到它们含有氮氧化物,主要是以NO的形式存在,在燃烧区不会分解,而是加入到燃料燃烧过程中已经产生的氮氧化物中。燃烧产物价格合理,但不是理想的压舱物。一方面,它们降低了燃烧区的最高温度和试剂的浓度,即减少了“热”NOx的形成,另一方面,它们向燃烧区添加了额外数量的一氧化氮,这与燃烧室燃烧过程中形成的一氧化氮加起来,也降低了方法的效率。在废气再循环过程中,当燃烧区的最高温度最高,燃烧前的燃料和压载物的整个体积混合最好时,它们对氮氧化物形成的影响最大。在燃烧过程中减少NO形成的最有效的压载物是二氧化碳,前提是二氧化碳在进入燃烧区之前与天然气进行充分的预分子混合。圣经16,表4,图2。
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