Mechanism of protective film formation during CO2 corrosion of X65 pipeline steel

Tong Li , Yongjin Yang , Kewei Gao , Minxu Lu
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引用次数: 37

Abstract

Electrochemical techniques, X-ray diffraction (XRD), and scanning electron microscopy (SEM) were applied to study the corrosion behaviors of X65 steel in static solution with carbon dioxide (CO2) at 65°C. The results show that iron carbonate (FeCO3) deposits on the steel surface as a corrosion product scale. This iron carbonate scale acts as a barrier to CO2 corrosion, and can reduce the general corrosion rate. The protection ability of the scale is closely related to the scale morphological characteristics.

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X65管线钢CO2腐蚀过程中保护膜形成机理
采用电化学技术、x射线衍射(XRD)和扫描电镜(SEM)研究了X65钢在65℃二氧化碳(CO2)静态溶液中的腐蚀行为。结果表明:碳酸铁(FeCO3)以腐蚀产物的形式沉积在钢表面;这种碳酸铁垢作为二氧化碳腐蚀的屏障,可以降低一般的腐蚀速率。水垢的防护能力与水垢的形态特征密切相关。
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