Thermodynamically study of phase formation of Ni-Ti-Si nanocomposites produced by self-propagating high-temperature synthesis method

H. Aghajani, Arvin Taghizadeh Tabrizi, Salva Arabpour Javadi, Mohammad Ehsan Taghizadeh Tabrizi, Aytak Homayouni, S. Behrangi
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引用次数: 3

Abstract

Understanding the phase formation mechanisms in self-propagating high-temperature synthesis from the thermodynamical aspect of view is important. In this study, the phase formation of the ternary system of nickel-titanium-silicon was studied by using the HSC software V6.0, and phase formation is predicted by calculating the adiabatic temperature of exothermic reaction between reagents. Then, by using X-ray diffractometer analysis, the results of the simulation were evaluated by experimental achievements. Results showed a good correlation between thermodynamical calculation and prediction with experimental. It could be concluded that the equilibrium mechanism is the dominant mechanism in phase formation in the SHS synthesis method. NiTiSi solid solution phase is obtained from the reaction between Ti5Si3 and Ni2Si and Ni.
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自蔓延高温合成法制备Ni-Ti-Si纳米复合材料相形成的热力学研究
从热力学角度理解自传播高温合成中的相形成机制是很重要的。本研究利用HSC软件V6.0对镍-钛-硅三元体系的相形成进行了研究,并通过计算试剂间放热反应的绝热温度来预测相的形成。然后利用x射线衍射仪分析,用实验成果对模拟结果进行评价。结果表明,热力学计算和预测结果与实验结果具有良好的相关性。综上所述,在SHS合成方法中,平衡机制是主要的相形成机制。由Ti5Si3与Ni2Si、Ni反应得到NiTiSi固溶体相。
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