The effect of synthesized Cu2O on the microbial corrosion inhibition of urban concrete sewer systems

Zahra Khademmodaresi, Fereshteh Bakhtiari, Mohammadmehdi Azizi
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引用次数: 1

Abstract

The microbial corrosion of reinforced concrete sewers was inhibited by synthesized cuprous oxide (Cu2O) nanoparticles. The antibacterial characteristics of Cu2O on Acidithiobacillus thiooxidans were investigated by temporal variation of pH, turbidity, and bacterial counting. Three reinforced concrete samples with different weight percentages of electrodeposited Cu2O (0.06 wt%, 0.055 wt %, 0.05 wt %) were used. The bacterial counting showed that the number of bacteria in samples with 0.06, 0.055, and 0.05 wt% of Cu2O was 4.82, 4.42, and 2.94 times lower than the blank sample (BS), respectively. After bacterial growth, the optical density measurement showed that the percentage of turbidity enhancement for samples with 0.06, 0.055, and 0.05 wt% of Cu2O were 108%, 118%, 165%, respectively, while it was 412% for the BS. Moreover, the pilot stage's pH monitoring revealed that the electrodeposited Cu2O lowered the concentration of hydronium between 7 to 81 times compared to the BS. Experiments indicated that slight changes in the amount of electrodeposited Cu2O lead to significant changes in samples' ability to hinder bacterial growth and microbial-induced corrosion.    
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合成Cu2O对城市混凝土下水道系统微生物缓蚀的影响
合成的氧化亚铜(Cu2O)纳米颗粒抑制了钢筋混凝土下水道的微生物腐蚀。通过pH值、浊度和细菌计数的时间变化研究了Cu2O对酸性硫氧化硫杆菌的抑菌特性。采用三种不同重量百分比(0.06 wt%, 0.055 wt%, 0.05 wt%)的电沉积Cu2O的钢筋混凝土样品。细菌计数结果显示,添加0.06、0.055和0.05 wt% Cu2O的样品中细菌数量分别比空白样品(BS)低4.82、4.42和2.94倍。细菌生长后,光密度测量结果显示,添加0.06、0.055、0.05 wt% Cu2O的样品浊度增强率分别为108%、118%、165%,而添加BS的样品浊度增强率为412%。此外,中试阶段的pH监测表明,与BS相比,电沉积Cu2O使水合氢离子浓度降低了7 ~ 81倍。实验表明,电沉积Cu2O量的微小变化会导致样品抑制细菌生长和微生物腐蚀的能力发生显著变化。
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