Gas-sensing characteristics of Li+-doped and undoped ZnO whiskers

M. Egashira, N. Kanehara, Y. Shimizu, H. Iwanaga
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引用次数: 42

Abstract

The gas-sensing characteristics of Li+-doped and undoped ZnO whiskers were investigated for 1% carbon monoxide, 1% hydrogen and 1% methane in air as a function of the operating temperature between 200 °C and 700 °C. The gas sensitivities of undoped ZnO whiskers were negligibly small to the sample gases because of their extremely low resistivities in air. However, the sensitivity was significantly enhanced by Li+-doping of the whiskers. The values of the enhanced sensitivities were comparable to those of the as-grown [101] SnO2 whiskers. But there was no definite correlation between the sensitivity and the morphology of the Li+-doped ZnO whiskers.

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Li+掺杂和未掺杂ZnO晶须的气敏特性
研究了Li+掺杂和未掺杂ZnO晶须在空气中对1%一氧化碳、1%氢气和1%甲烷的气敏特性随工作温度在200 ~ 700℃之间的变化规律。未掺杂ZnO晶须在空气中的电阻率极低,对样品气体的气敏性小到可以忽略不计。然而,在晶须中掺杂Li+后,灵敏度显著提高。增强的灵敏度值与生长[101]的SnO2晶须相当。但掺杂Li+的ZnO晶须的形貌与灵敏度之间没有明确的相关性。
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