首页 > 最新文献

Manufacturing Letters最新文献

英文 中文
Experimental validation of the amplitude ratio as a metric for milling stability identification 将振幅比作为铣削稳定性识别指标的实验验证
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.078
Mark A. Rubeo
This paper presents the experimental validation of the amplitude ratio, a metric for milling stability identification. The amplitude ratio quantifies the severity of chatter by comparing the amplitude of the expected frequency content of a milling signal (i.e., tooth passing frequency, runout frequency, and harmonics) to the amplitude of the chatter frequency, if present. Through multiple iterations of a milling time domain simulation, the amplitude ratio diagram, which characterizes stable and unstable milling behavior over a range of spindle speeds and axial depths of cut, may be generated. In this paper, a comparison of the simulated and measured amplitude ratios for a series of milling test cuts is presented. It is shown that the amplitude ratio is suitable for identifying milling stability in both simulations and experiments. Additionally, it is shown that through judicious selection of low-cost sensors, implementation of the amplitude ratio is cost efficient. Direct comparison of the simulated and measured amplitude ratios demonstrates the effectiveness of the approach.
本文介绍了振幅比的实验验证,这是一种用于铣削稳定性识别的指标。振幅比通过比较铣削信号的预期频率内容(即齿过频率、跳动频率和谐波)的振幅与颤振频率(如果存在)的振幅来量化颤振的严重程度。通过多次迭代铣削时域仿真,可以生成幅值比图,该图描述了在一定主轴转速和轴向切削深度范围内稳定和不稳定的铣削行为。本文对一系列铣削测试切削的模拟振幅比和测量振幅比进行了比较。结果表明,在模拟和实验中,振幅比都适用于识别铣削稳定性。此外,研究还表明,通过明智地选择低成本传感器,振幅比的实施具有成本效益。对模拟和测量的振幅比进行直接比较,证明了该方法的有效性。
{"title":"Experimental validation of the amplitude ratio as a metric for milling stability identification","authors":"Mark A. Rubeo","doi":"10.1016/j.mfglet.2024.09.078","DOIUrl":"10.1016/j.mfglet.2024.09.078","url":null,"abstract":"<div><div>This paper presents the experimental validation of the amplitude ratio, a metric for milling stability identification. The amplitude ratio quantifies the severity of chatter by comparing the amplitude of the expected frequency content of a milling signal (i.e., tooth passing frequency, runout frequency, and harmonics) to the amplitude of the chatter frequency, if present. Through multiple iterations of a milling time domain simulation, the amplitude ratio diagram, which characterizes stable and unstable milling behavior over a range of spindle speeds and axial depths of cut, may be generated. In this paper, a comparison of the simulated and measured amplitude ratios for a series of milling test cuts is presented. It is shown that the amplitude ratio is suitable for identifying milling stability in both simulations and experiments. Additionally, it is shown that through judicious selection of low-cost sensors, implementation of the amplitude ratio is cost efficient. Direct comparison of the simulated and measured amplitude ratios demonstrates the effectiveness of the approach.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 610-618"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Femtosecond laser joining of Stellite and stainless steel 飞秒激光连接人造卫星和不锈钢
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.039
David Fieser , Lingyue Zhang , Matthew Yao , Hugh Shortt , Peter Liaw , Anming Hu
This research explores the practicality of fusing Stellite 6, a cobalt-chromium alloy known for its high performance, with stainless steel, utilizing various laser welding approaches. The primary challenge addressed is the joining of dissimilar materials, which presents obstacles such as divergent melting points and disparate coefficients of thermal expansion. The aim is to achieve a metallurgical bond between Stellite and stainless steel that retains desirable properties. The study employs both continuous wave and femtosecond laser welding techniques, subjecting the resultant joints to rigorous analysis to assess their impact on the properties of the bond. Initial tensile testing delineated the intrinsic mechanical characteristics of the materials, revealing that while Stellite exhibits a lower ultimate tensile strength, it compensates with greater elongation compared to stainless steel. The use of continuous wave laser welding proved to be capable of creating the bond; however, it also precipitated a considerable decline in the tensile strength of the Stellite component as a result of the thermal processing involved. In contrast, femtosecond laser welding emerged as a more effective method, enhancing the joint’s overall strength and ductility. This improvement is attributed to the femtosecond laser’s precise control over thermal exposure, which confines the heat to the intended weld zone, thereby safeguarding the adjacent material from damage. Further insights were gleaned from Scanning Electron Microscopy, which showed a preferable intergranular fracture in samples welded with the femtosecond laser—a feature typically associated with ductile failure modes. The femtosecond laser welding approach culminated in a joint efficiency of 53.7%, mirroring the innate yield strength of the Stellite wire. This outcome suggests that such welded joints possess the requisite robustness for practical deployment, thus underscoring the potential of femtosecond laser welding in applications requiring the joining of Stellite to stainless steel.
这项研究探讨了利用各种激光焊接方法将以高性能著称的钴铬合金 Stellite 6 与不锈钢熔合的实用性。所面临的主要挑战是异种材料的连接,这就带来了熔点不同和热膨胀系数不同等障碍。目的是在人造卫星和不锈钢之间实现冶金结合,并保持理想的性能。研究采用了连续波和飞秒激光焊接技术,并对焊接接头进行了严格分析,以评估其对粘接性能的影响。最初的拉伸测试确定了材料的固有机械特性,结果表明,虽然 Stellite 的极限拉伸强度较低,但与不锈钢相比,它能以更大的伸长率进行补偿。事实证明,使用连续波激光焊接能够形成粘接;但是,由于涉及热加工,Stellite 组件的抗拉强度也大幅下降。相比之下,飞秒激光焊接是一种更有效的方法,它提高了接头的整体强度和延展性。这种改进归功于飞秒激光对热暴露的精确控制,它将热量限制在预定的焊接区域,从而保护了邻近材料免受损坏。扫描电子显微镜还提供了更多信息,显示飞秒激光焊接的样品具有更佳的晶间断裂--这通常与韧性破坏模式有关。飞秒激光焊接方法的接合效率高达 53.7%,反映了 Stellite 金属丝与生俱来的屈服强度。这一结果表明,这种焊接接头具有实际应用所需的坚固性,从而凸显了飞秒激光焊接在需要将斯特莱特合金与不锈钢连接的应用中的潜力。
{"title":"Femtosecond laser joining of Stellite and stainless steel","authors":"David Fieser ,&nbsp;Lingyue Zhang ,&nbsp;Matthew Yao ,&nbsp;Hugh Shortt ,&nbsp;Peter Liaw ,&nbsp;Anming Hu","doi":"10.1016/j.mfglet.2024.09.039","DOIUrl":"10.1016/j.mfglet.2024.09.039","url":null,"abstract":"<div><div>This research explores the practicality of fusing Stellite 6, a cobalt-chromium alloy known for its high performance, with stainless steel, utilizing various laser welding approaches. The primary challenge addressed is the joining of dissimilar materials, which presents obstacles such as divergent melting points and disparate coefficients of thermal expansion. The aim is to achieve a metallurgical bond between Stellite and stainless steel that retains desirable properties. The study employs both continuous wave and femtosecond laser welding techniques, subjecting the resultant joints to rigorous analysis to assess their impact on the properties of the bond. Initial tensile testing delineated the intrinsic mechanical characteristics of the materials, revealing that while Stellite exhibits a lower ultimate tensile strength, it compensates with greater elongation compared to stainless steel. The use of continuous wave laser welding proved to be capable of creating the bond; however, it also precipitated a considerable decline in the tensile strength of the Stellite component as a result of the thermal processing involved. In contrast, femtosecond laser welding emerged as a more effective method, enhancing the joint’s overall strength and ductility. This improvement is attributed to the femtosecond laser’s precise control over thermal exposure, which confines the heat to the intended weld zone, thereby safeguarding the adjacent material from damage. Further insights were gleaned from Scanning Electron Microscopy, which showed a preferable intergranular fracture in samples welded with the femtosecond laser—a feature typically associated with ductile failure modes. The femtosecond laser welding approach culminated in a joint efficiency of 53.7%, mirroring the innate yield strength of the Stellite wire. This outcome suggests that such welded joints possess the requisite robustness for practical deployment, thus underscoring the potential of femtosecond laser welding in applications requiring the joining of Stellite to stainless steel.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 332-338"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of a wireless smart sensor system and case study on lifting risk assessment 开发无线智能传感器系统和起重风险评估案例研究
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.027
Vignesh Selvaraj , Aditya Nagaraj , Benjamin Gregory Whiffen, Sangkee Min
With the widespread adoption of Industry 4.0 and smart manufacturing concepts across industries, sensor development, system integration, and data analysis have become important aspects of efficient manufacturing operations. In addition to monitoring the performance of machines, significant importance is given to human condition monitoring in factories, using body-worn sensors to ensure the well-being of workers and for injury prevention. This research presents the development of a body-worn sensor system capable of sampling acceleration and rotation data up to 400 Hz and wirelessly transmitting the data over Bluetooth Low Energy (BLE). Further, the communication protocols for data acquisition, data communication within the device, Real Time Operating System (RTOS) programming, and multi-threading are described. This system is designed in such a way that multiple devices can be connected to the Data acquisition (DAQ) system simultaneously, and data is collected from the sensors in a synchronized manner. This information is valuable for the wider adoption of sensor systems for human condition monitoring in industry. Lastly, to test the system’s capabilities, a case study of lifting risk assessment is presented, where data collected from the accelerometer and gyroscope are used to determine a relative estimate of the physical stress associated with a manual lifting task by using different machine learning (ML) algorithms. The case study highlights how sensor placement, feature extraction, and sensor types influence machine learning models. As the sensor system can perform computations on the edge, a framework to carry out real-time lifting risk assessment using lightweight algorithms and the most important data features is proposed.
随着工业 4.0 和智能制造概念在各行各业的广泛应用,传感器开发、系统集成和数据分析已成为高效生产运营的重要方面。除了监测机器的性能外,工厂中的人体状态监测也受到了高度重视,通过使用佩戴式传感器来确保工人的健康并预防工伤。本研究介绍了一种体戴式传感器系统的开发情况,该系统能够以高达 400 Hz 的频率对加速度和旋转数据进行采样,并通过蓝牙低功耗 (BLE) 无线传输数据。此外,还介绍了数据采集的通信协议、设备内的数据通信、实时操作系统(RTOS)编程和多线程。该系统的设计方式使多个设备可以同时连接到数据采集(DAQ)系统,并以同步方式从传感器采集数据。这些信息对于在工业领域更广泛地采用传感器系统进行人体状态监测非常有价值。最后,为了测试该系统的能力,介绍了一个起重风险评估案例研究,通过使用不同的机器学习(ML)算法,使用从加速计和陀螺仪收集的数据来确定与人工起重任务相关的物理压力的相对估计值。该案例研究强调了传感器位置、特征提取和传感器类型对机器学习模型的影响。由于传感器系统可以在边缘执行计算,因此提出了一个使用轻量级算法和最重要数据特征进行实时起重风险评估的框架。
{"title":"Development of a wireless smart sensor system and case study on lifting risk assessment","authors":"Vignesh Selvaraj ,&nbsp;Aditya Nagaraj ,&nbsp;Benjamin Gregory Whiffen,&nbsp;Sangkee Min","doi":"10.1016/j.mfglet.2024.09.027","DOIUrl":"10.1016/j.mfglet.2024.09.027","url":null,"abstract":"<div><div>With the widespread adoption of Industry 4.0 and smart manufacturing concepts across industries, sensor development, system integration, and data analysis have become important aspects of efficient manufacturing operations. In addition to monitoring the performance of machines, significant importance is given to human condition monitoring in factories, using body-worn sensors to ensure the well-being of workers and for injury prevention. This research presents the development of a body-worn sensor system capable of sampling acceleration and rotation data up to 400 Hz and wirelessly transmitting the data over Bluetooth Low Energy (BLE). Further, the communication protocols for data acquisition, data communication within the device, Real Time Operating System (RTOS) programming, and multi-threading are described. This system is designed in such a way that multiple devices can be connected to the Data acquisition (DAQ) system simultaneously, and data is collected from the sensors in a synchronized manner. This information is valuable for the wider adoption of sensor systems for human condition monitoring in industry. Lastly, to test the system’s capabilities, a case study of lifting risk assessment is presented, where data collected from the accelerometer and gyroscope are used to determine a relative estimate of the physical stress associated with a manual lifting task by using different machine learning (ML) algorithms. The case study highlights how sensor placement, feature extraction, and sensor types influence machine learning models. As the sensor system can perform computations on the edge, a framework to carry out real-time lifting risk assessment using lightweight algorithms and the most important data features is proposed.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 229-240"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Framework for LLM applications in manufacturing 制造业应用 LLM 的框架
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.030
Cristian I. Garcia, Marcus A. DiBattista, Tomás A. Letelier, Hunter D. Halloran, Jaime A. Camelio
In the era of Industry 4.0, the proliferation of data within manufacturing environments has presented both unprecedented opportunities and challenges. This paper introduces a framework that capitalizes on the capabilities of Large Language Models (LLMs) to revolutionize data integration and decision-making processes in manufacturing systems. Addressing the critical need for efficient data management, our framework streamlines the consolidation, processing, and generation of responses to essential inquiries, thus enhancing manufacturers’ capabilities to extract valuable insights. The focus of this paper is twofold. First to establish a framework for the use of LLM applications in manufacturing settings. Secondly, to provide an overview of the manufacturing connection between data, AI, and chat-bots, while also addressing a few pain points identified from the manufacturing literature. The paper then introduces FILLIS (Factory Integrated Logic and Language Interface System), a Large Language Model assistant, through a compelling case study. FILLIS showcases remarkable versatility, excelling in tasks ranging from elucidating machine operations to language translation. The study underscores FILLIS’s proficiency in handling specific contexts, answering questions from uploaded documents with precision. However, inherent limitations surface in tasks involving mathematical operations, emphasizing the need for external agents in specific scenarios. This pivotal opportunity is explored in the proposed framework as it advocates for integrating external agents alongside LLMs, creating a more versatile and comprehensive assistant tool. The findings of this paper and proposed framework position LLMs as transformative tools for intelligent data processing.
在工业 4.0 时代,制造环境中数据的激增带来了前所未有的机遇和挑战。本文介绍了一种利用大型语言模型(LLM)功能的框架,以彻底改变制造系统中的数据集成和决策流程。为了满足高效数据管理的关键需求,我们的框架简化了重要查询的整合、处理和生成响应,从而提高了制造商提取有价值见解的能力。本文的重点有两个方面。首先,为在制造环境中使用 LLM 应用程序建立一个框架。其次,概述数据、人工智能和聊天机器人之间的制造业联系,同时解决从制造业文献中发现的几个痛点。然后,本文通过一个引人注目的案例研究介绍了大型语言模型助手 FILLIS(工厂集成逻辑和语言接口系统)。FILLIS 展示了非凡的多功能性,在阐释机器操作和语言翻译等任务中表现出色。这项研究强调了 FILLIS 在处理特定语境方面的能力,它能准确回答上传文档中的问题。然而,在涉及数学运算的任务中,其固有的局限性就显现出来了,这就强调了在特定场景中对外部代理的需求。本文提出的框架探讨了这一关键机遇,主张将外部代理与 LLMs 整合在一起,创建一个功能更全面、更综合的辅助工具。本文的研究结果和拟议框架将 LLMs 定位为智能数据处理的变革性工具。
{"title":"Framework for LLM applications in manufacturing","authors":"Cristian I. Garcia,&nbsp;Marcus A. DiBattista,&nbsp;Tomás A. Letelier,&nbsp;Hunter D. Halloran,&nbsp;Jaime A. Camelio","doi":"10.1016/j.mfglet.2024.09.030","DOIUrl":"10.1016/j.mfglet.2024.09.030","url":null,"abstract":"<div><div>In the era of Industry 4.0, the proliferation of data within manufacturing environments has presented both unprecedented opportunities and challenges. This paper introduces a framework that capitalizes on the capabilities of Large Language Models (LLMs) to revolutionize data integration and decision-making processes in manufacturing systems. Addressing the critical need for efficient data management, our framework streamlines the consolidation, processing, and generation of responses to essential inquiries, thus enhancing manufacturers’ capabilities to extract valuable insights. The focus of this paper is twofold. First to establish a framework for the use of LLM applications in manufacturing settings. Secondly, to provide an overview of the manufacturing connection between data, AI, and chat-bots, while also addressing a few pain points identified from the manufacturing literature. The paper then introduces FILLIS (<em>Factory Integrated Logic and Language Interface System</em>), a Large Language Model assistant, through a compelling case study. FILLIS showcases remarkable versatility, excelling in tasks ranging from elucidating machine operations to language translation. The study underscores FILLIS’s proficiency in handling specific contexts, answering questions from uploaded documents with precision. However, inherent limitations surface in tasks involving mathematical operations, emphasizing the need for external agents in specific scenarios. This pivotal opportunity is explored in the proposed framework as it advocates for integrating external agents alongside LLMs, creating a more versatile and comprehensive assistant tool. The findings of this paper and proposed framework position LLMs as transformative tools for intelligent data processing.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 253-263"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434278","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Iterative correction of robotic grinding using spatial feedback for precision applications 利用空间反馈对机器人打磨进行迭代修正,以实现精确应用
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.031
Philip A. Olubodun, Joseph D. Fischer, Douglas A. Bristow
Since the advent of robots, many tasks that were originally performed by humans have now been tasked to industrial robots. From a manufacturing standpoint, robots have primarily been used in pick-and-place or other non-machining operations that require high repeatability. However, with the increasing availability of CAD/CAM software and the development of high-precision metrology, comes the opportunity to integrate robots into a wider variety of manufacturing processes through the use of feedback control. One such machining operation that is being explored is precision grinding of metal parts. Most other work in this area has focused on force regulation to improve grind quality; however, this paper takes a different approach. In this work, an Iterative Learning Control (ILC) algorithm is implemented to correct the geometric error directly by altering the toolpath trajectory. Specifically, in this framework, a conservative initial cutting trajectory is implemented using a 6-DoF robotic grinding system, and the resulting part geometry is measured via a high-precision laser scanner. Based on the resultant geometric error, the toolpath is corrected and then rerun on the part. This process is then repeated iteratively until sufficient accuracy is achieved. Due to the inability to replace material in overground regions, the controller is designed with an emphasis on reducing overshoot which cannot be corrected. The controller is experimentally validated by grinding an elliptical pocket which meets FAA specifications for corrosion removal in aircraft. The results showed that within seven iterations the entire error surface could be brought to a tolerance of ±0.150 mm for the given geometry.
自从机器人问世以来,许多原本由人类完成的任务现在都交给了工业机器人。从制造的角度来看,机器人主要用于拾放或其他需要高重复性的非加工操作。然而,随着 CAD/CAM 软件的日益普及和高精度计量学的发展,机器人有机会通过使用反馈控制,集成到更广泛的制造流程中。目前正在探索的一种加工操作是金属零件的精密打磨。该领域的大多数其他工作都侧重于力的调节,以提高打磨质量;但本文采用了不同的方法。本文采用迭代学习控制 (ILC) 算法,通过改变刀具轨迹直接修正几何误差。具体来说,在此框架下,使用 6-DoF 机器人磨削系统实现保守的初始切削轨迹,并通过高精度激光扫描仪测量由此产生的零件几何形状。根据由此产生的几何误差,对刀具轨迹进行修正,然后在零件上重新运行。这一过程反复进行,直到达到足够的精度。由于无法替换过磨区域的材料,控制器的设计重点是减少无法修正的过冲。该控制器通过磨削符合美国联邦航空局飞机除锈规范的椭圆形凹槽进行了实验验证。结果表明,对于给定的几何形状,在七次迭代中,整个误差面的公差可达到 ±0.150 毫米。
{"title":"Iterative correction of robotic grinding using spatial feedback for precision applications","authors":"Philip A. Olubodun,&nbsp;Joseph D. Fischer,&nbsp;Douglas A. Bristow","doi":"10.1016/j.mfglet.2024.09.031","DOIUrl":"10.1016/j.mfglet.2024.09.031","url":null,"abstract":"<div><div>Since the advent of robots, many tasks that were originally performed by humans have now been tasked to industrial robots. From a manufacturing standpoint, robots have primarily been used in pick-and-place or other non-machining operations that require high repeatability. However, with the increasing availability of CAD/CAM software and the development of high-precision metrology, comes the opportunity to integrate robots into a wider variety of manufacturing processes through the use of feedback control. One such machining operation that is being explored is precision grinding of metal parts. Most other work in this area has focused on force regulation to improve grind quality; however, this paper takes a different approach. In this work, an Iterative Learning Control (ILC) algorithm is implemented to correct the geometric error directly by altering the toolpath trajectory. Specifically, in this framework, a conservative initial cutting trajectory is implemented using a 6-DoF robotic grinding system, and the resulting part geometry is measured via a high-precision laser scanner. Based on the resultant geometric error, the toolpath is corrected and then rerun on the part. This process is then repeated iteratively until sufficient accuracy is achieved. Due to the inability to replace material in overground regions, the controller is designed with an emphasis on reducing overshoot which cannot be corrected. The controller is experimentally validated by grinding an elliptical pocket which meets FAA specifications for corrosion removal in aircraft. The results showed that within seven iterations the entire error surface could be brought to a tolerance of ±0.150 mm for the given geometry.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 264-269"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of milling interventions on the geometry of wall-shaped structures in hybrid wire-arc direct energy deposition 混合线弧直接能量沉积中铣削干预对壁状结构几何形状的影响
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.096
Akshar Kota, Shohom Bose-Bandyopadhyay, Asif Rashid, Shreyes N. Melkote
The Hybrid Wire-Arc Direct Energy Deposition (Hybrid Wire-Arc DED) process integrates Wire-Arc Direct Energy Deposition (Wire-Arc DED) with machining (typically milling) interventions, offering the potential for creating intricate geometries and finished surfaces. However, if milling is employed as a hybrid intervention rather than as a final part-finishing process, the interplay between these processes remains under-investigated. This paper examines the influence of milling interventions on the geometry of a wall-shaped structure, quantified by the transverse cross-sectional width, built using a Hybrid Wire-Arc DED. Through experiments on mild steel, the underlying causes of observed wall-width variations are analyzed. Initial observations suggested that thermo-mechanical deformations from milling influence the width variations. However, evidence indicates the significant role of additional remelting cycles experienced by the milled surface layer during subsequent layer depositions. The study also reveals that the observed increase in wall width for each milling intervention occurs at approximately the same depth below the milled surface. A mechanistic explanation for this observation is given. Crucially, the findings suggest that unless milling is done at higher frequencies, like after each layer deposition, the resultant unevenness might render the Hybrid Wire-Arc DED process less efficient in terms of surface quality and dimensional accuracy than its non-hybrid counterpart.
线-弧混合直接能量沉积(Hybrid Wire-Arc DED)工艺将线-弧直接能量沉积(Wire-Arc DED)与机加工(通常是铣削)干预集成在一起,为创造复杂的几何形状和精加工表面提供了可能性。然而,如果将铣削作为一种混合干预而不是作为最终的零件精加工工艺来使用,那么这些工艺之间的相互作用仍未得到充分研究。本文研究了铣削干预对墙形结构几何形状的影响,该几何形状由横向截面宽度量化,使用混合线弧钻铣制造。通过对低碳钢的实验,分析了观察到的壁宽变化的根本原因。初步观察表明,铣削产生的热机械变形影响了宽度变化。然而,有证据表明,铣削表面层在后续层沉积过程中经历的额外重熔循环起了重要作用。研究还发现,每次铣削过程中观察到的壁宽增加都发生在铣削表面以下大致相同的深度。研究给出了这一观察结果的机理解释。最重要的是,研究结果表明,除非以更高的频率进行铣削,例如在每层沉积后进行铣削,否则由此产生的不平整可能会使混合线-电弧 DED 工艺在表面质量和尺寸精度方面的效率低于非混合工艺。
{"title":"Influence of milling interventions on the geometry of wall-shaped structures in hybrid wire-arc direct energy deposition","authors":"Akshar Kota,&nbsp;Shohom Bose-Bandyopadhyay,&nbsp;Asif Rashid,&nbsp;Shreyes N. Melkote","doi":"10.1016/j.mfglet.2024.09.096","DOIUrl":"10.1016/j.mfglet.2024.09.096","url":null,"abstract":"<div><div>The Hybrid Wire-Arc Direct Energy Deposition (Hybrid Wire-Arc DED) process integrates Wire-Arc Direct Energy Deposition (Wire-Arc DED) with machining (typically milling) interventions, offering the potential for creating intricate geometries and finished surfaces. However, if milling is employed as a hybrid intervention rather than as a final part-finishing process, the interplay between these processes remains under-investigated. This paper examines the influence of milling interventions on the geometry of a wall-shaped structure, quantified by the transverse cross-sectional width, built using a Hybrid Wire-Arc DED. Through experiments on mild steel, the underlying causes of observed wall-width variations are analyzed. Initial observations suggested that thermo-mechanical deformations from milling influence the width variations. However, evidence indicates the significant role of additional remelting cycles experienced by the milled surface layer during subsequent layer depositions. The study also reveals that the observed increase in wall width for each milling intervention occurs at approximately the same depth below the milled surface. A mechanistic explanation for this observation is given. Crucially, the findings suggest that unless milling is done at higher frequencies, like after each layer deposition, the resultant unevenness might render the Hybrid Wire-Arc DED process less efficient in terms of surface quality and dimensional accuracy than its non-hybrid counterpart.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 772-779"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SLM-printed lattice structures with tapered vertical struts: Design, simulation and experimentation 带有锥形垂直支柱的 SLM 印刷晶格结构:设计、模拟和实验
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.100
Daniyar Syrlybayev, Andrei Yankin, Asma Perveen, Didier Talamona
This study, designed new lattice structures using vertical struts that taper off. The degree of tapering was controlled using a parameter called “α”. To fabricate these structures, 3D-printing technology known as SLM (selected laser melting) was used. These lattice structures were also simulated using finite element analysis (FEA) and tested experimentally. The used material was 316L stainless steel. Stress–strain curves provided insights into their deformation behavior, revealing a noteworthy occurrence: the unloading modulus exceeded the loading modulus. The mechanical properties of these absolute and density-normalized lattice structures, demonstrated improvement with higher values of the shape parameter α. Yield stress increased by 31 %, loading modulus by 21 %, and energy absorption by 33 %. Specific yield stress improved by 24 %, and specific energy absorption increased by 27 %. While simulation and experimental results exhibited a correlation, they differed significantly in modulus estimation, with simulations overestimating it by more than 30 %.
这项研究利用逐渐变细的垂直支柱设计了新的晶格结构。锥度由一个名为 "α "的参数控制。为了制造这些结构,使用了被称为 SLM(选择性激光熔融)的 3D 打印技术。还使用有限元分析(FEA)对这些晶格结构进行了模拟,并进行了实验测试。所用材料为 316L 不锈钢。应力-应变曲线揭示了它们的变形行为,并发现了一个值得注意的现象:卸载模量超过了加载模量。这些绝对和密度归一化晶格结构的机械性能随着形状参数 α 值的提高而得到改善,屈服应力提高了 31%,加载模量提高了 21%,能量吸收提高了 33%。比屈服应力提高了 24%,比能量吸收提高了 27%。虽然模拟和实验结果显示出相关性,但在模量估计方面却存在显著差异,模拟结果高估了 30% 以上。
{"title":"SLM-printed lattice structures with tapered vertical struts: Design, simulation and experimentation","authors":"Daniyar Syrlybayev,&nbsp;Andrei Yankin,&nbsp;Asma Perveen,&nbsp;Didier Talamona","doi":"10.1016/j.mfglet.2024.09.100","DOIUrl":"10.1016/j.mfglet.2024.09.100","url":null,"abstract":"<div><div>This study, designed new lattice structures using vertical struts that taper off. The degree of tapering was controlled using a parameter called “α”. To fabricate these structures, 3D-printing technology known as SLM (selected laser melting) was used. These lattice structures were also simulated using finite element analysis (FEA) and tested experimentally. The used material was 316L stainless steel. Stress–strain curves provided insights into their deformation behavior, revealing a noteworthy occurrence: the unloading modulus exceeded the loading modulus. The mechanical properties of these absolute and density-normalized lattice structures, demonstrated improvement with higher values of the shape parameter α. Yield stress increased by 31 %, loading modulus by 21 %, and energy absorption by 33 %. Specific yield stress improved by 24 %, and specific energy absorption increased by 27 %. While simulation and experimental results exhibited a correlation, they differed significantly in modulus estimation, with simulations overestimating it by more than 30 %.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 803-809"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Applying design complexity metrics for post-processing cost modeling in metal additive manufacturing 在金属增材制造中应用设计复杂性指标进行后处理成本建模
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.098
Riccardo C. Clemente, Seyed A. Niknam
The recent Additive manufacturing (AM) literature has primarily concentrated on exploring new avenues for improving the current technology and its applicability. It has also delved into research investments aimed at addressing the last remaining prediction challenges associated with current AM processes, particularly focusing to surface quality, accuracy, and internal composition. These limitations can often be mitigated though the application of post-processing techniques. Such techniques are often very costly both in time and monetary terms.
When it comes to the impact that shape complexity has on post-fabrication costs for AM parts, a gap in the literature is apparent. In recent years, more attention has been devoted to researching a general shape complexity metric. It has been suggested in the literature to combine multiple of complexity metrics techniques, to reach more comprehensive model. This aspect has not received enough attention in previous works. In addition, the relationship between shape complexity and post-processing costs has not been assessed. And there are no predictive models for post-processing costs based on complexity.
In this study, AM shapes for prototyping application are analysed. In this regard, previously established complexity metrics are used, together with expert’s assessments of post-processing costs, to create a model capable of predicting post-processing costs. This is achieved through a regression analysis using costs and complexity metrics values. The result of this research are two regression models, named 7 V and Vol/Sur Models, capable of predicting post-processing costs for AM parts produced through DMLS techniques with SS316L stainless steel powder. The accuracy of the two models is discussed.
近期的增材制造(AM)文献主要集中在探索改进当前技术及其适用性的新途径。此外,还深入开展研究投资,旨在解决与当前增材制造工艺相关的最后遗留的预测难题,尤其侧重于表面质量、精度和内部组成。这些限制通常可以通过应用后处理技术来缓解。当谈到形状复杂性对 AM 零件后加工成本的影响时,文献中的空白是显而易见的。近年来,越来越多的人开始关注通用形状复杂性指标的研究。有文献建议结合多种复杂度度量技术,以建立更全面的模型。在以往的研究中,这方面还没有得到足够的重视。此外,形状复杂度与后处理成本之间的关系也没有得到评估。本研究分析了用于原型制作的 AM 形状。在这方面,使用了之前建立的复杂性指标,并结合专家对后处理成本的评估,创建了一个能够预测后处理成本的模型。这是通过使用成本和复杂性指标值进行回归分析实现的。这项研究的成果是两个回归模型,分别命名为 7 V 和 Vol/Sur 模型,能够预测使用 SS316L 不锈钢粉末通过 DMLS 技术生产的 AM 零件的后处理成本。本文讨论了这两个模型的准确性。
{"title":"Applying design complexity metrics for post-processing cost modeling in metal additive manufacturing","authors":"Riccardo C. Clemente,&nbsp;Seyed A. Niknam","doi":"10.1016/j.mfglet.2024.09.098","DOIUrl":"10.1016/j.mfglet.2024.09.098","url":null,"abstract":"<div><div>The recent Additive manufacturing (AM) literature has primarily concentrated on exploring new avenues for improving the current technology and its applicability. It has also delved into research investments aimed at addressing the last remaining prediction challenges associated with current AM processes, particularly focusing to surface quality, accuracy, and internal composition. These limitations can often be mitigated though the application of post-processing techniques. Such techniques are often very costly both in time and monetary terms.</div><div>When it comes to the impact that shape complexity has on post-fabrication costs for AM parts, a gap in the literature is apparent. In recent years, more attention has been devoted to researching a general shape complexity metric. It has been suggested in the literature to combine multiple of complexity metrics techniques, to reach more comprehensive model. This aspect has not received enough attention in previous works. In addition, the relationship between shape complexity and post-processing costs has not been assessed. And there are no predictive models for post-processing costs based on complexity.</div><div>In this study, AM shapes for prototyping application are analysed. In this regard, previously established complexity metrics are used, together with expert’s assessments of post-processing costs, to create a model capable of predicting post-processing costs. This is achieved through a regression analysis using costs and complexity metrics values. The result of this research are two regression models, named 7 V and Vol/Sur Models, capable of predicting post-processing costs for AM parts produced through DMLS techniques with SS316L stainless steel powder. The accuracy of the two models is discussed.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 787-794"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A critical assessment of the onset strain of densification in the evaluation of energy absorption for additively manufactured cellular materials 在评估增材制造蜂窝材料的能量吸收时对致密化起始应变进行严格评估
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.089
Mandar Shinde, Irving E. Ramirez-Chavez, Alexander Potts, Dhruv Bhate
Densification strain is an essential parameter in the characterization of energy absorption of additively manufactured cellular structures. In addition to its own merits as a metric that indicates usable stroke length for energy absorbers, it is central to the computation of energy absorbed by the structure. However, at least four different approaches have been used in the literature, each with its own limitations. In this work, a critical review of these approaches is first presented. While the maximum efficiency approach has been demonstrated to be optimal for cellular foams, this work shows how, for some additively manufactured cellular materials, it can fail to estimate densification strain accurately due to its sensitivity to instantaneous stress values in the plateau region. An alternative method is proposed in this work that leverages peak stress instead to determine the onset strain of densification and is shown to be consistently accurate across a range of cellular materials. The method is validated with the results from an experimental study of energy absorption in six different types of cellular structures across three relative densities, with identical geometries fabricated in two different base materials and processes: AlSi10Mg with Laser Powder Bed Fusion, and Nylon-12 with Selective Laser Sintering.
致密化应变是表征加成制造蜂窝结构能量吸收的一个重要参数。除了作为表示能量吸收器可用冲程长度的指标本身的优点外,它还是计算结构能量吸收的核心。然而,文献中至少使用了四种不同的方法,每种方法都有其自身的局限性。在这项工作中,首先对这些方法进行了严格审查。虽然最大效率法已被证明是蜂窝泡沫的最佳方法,但本研究表明,对于某些添加制造的蜂窝材料,由于其对高原区瞬时应力值的敏感性,该方法可能无法准确估计致密化应变。本研究提出了一种替代方法,利用峰值应力来确定致密化的起始应变,结果表明该方法在一系列蜂窝材料中始终保持精确。该方法通过对三种相对密度的六种不同类型蜂窝结构的能量吸收实验研究结果进行了验证,这些蜂窝结构采用两种不同的基体材料和工艺制造而成,具有相同的几何形状:采用激光粉末床熔融技术的 AlSi10Mg 和采用选择性激光烧结技术的尼龙-12。
{"title":"A critical assessment of the onset strain of densification in the evaluation of energy absorption for additively manufactured cellular materials","authors":"Mandar Shinde,&nbsp;Irving E. Ramirez-Chavez,&nbsp;Alexander Potts,&nbsp;Dhruv Bhate","doi":"10.1016/j.mfglet.2024.09.089","DOIUrl":"10.1016/j.mfglet.2024.09.089","url":null,"abstract":"<div><div>Densification strain is an essential parameter in the characterization of energy absorption of additively manufactured cellular structures. In addition to its own merits as a metric that indicates usable stroke length for energy absorbers, it is central to the computation of energy absorbed by the structure. However, at least four different approaches have been used in the literature, each with its own limitations. In this work, a critical review of these approaches is first presented. While the maximum efficiency approach has been demonstrated to be optimal for cellular foams, this work shows how, for some additively manufactured cellular materials, it can fail to estimate densification strain accurately due to its sensitivity to instantaneous stress values in the plateau region. An alternative method is proposed in this work that leverages peak stress instead to determine the onset strain of densification and is shown to be consistently accurate across a range of cellular materials. The method is validated with the results from an experimental study of energy absorption in six different types of cellular structures across three relative densities, with identical geometries fabricated in two different base materials and processes: AlSi10Mg with Laser Powder Bed Fusion, and Nylon-12 with Selective Laser Sintering.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 708-719"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plasmonic image reproduction with solid-state superionic stamping (S4) 利用固态超离子冲压技术再现等离子图像 (S4)
IF 1.9 Q3 ENGINEERING, MANUFACTURING Pub Date : 2024-10-01 DOI: 10.1016/j.mfglet.2024.09.073
Boqiang Qian, Papia Sultana, Ricardo Toro, Glennys Mensing, Placid Ferreira
Traditional top-down approaches for producing metallic nanostructures, despite being capable of producing arbitrary 2-D shapes, often use vacuum-based deep sub-micron lithographic fabrication technologies. This makes their use for single-use devices like chemical and bio-sensing substrates difficult to economically justify. Here, the authors demonstrate a manufacturing pathway that only uses such techniques to produce a master. This reusable master, coupled with a unique and facile electrochemical imprinting process, Solid-State Superionic Stamping (S4), is used to produce several replicated metallic nanostructures, thus demonstrating an economically feasible manufacturing pathway for single-use, nano-enabled devices.
This paper uses plasmonic image reproduction as an easy-to-visualize proxy for single-use devices such as plasmonic sensors and Surface Enhanced Raman Spectroscopy (SERS) substrates that require nanopatterned metallic structures. It demonstrates a process for replicating a picture by a set of metallic structures that plasmonically produce the desired colors locally. It uses a digitizing computational tool, direct-write Two-Photon Lithography (TPL) and a dry-etch process to rapidly produce a silicon master. This master is used to hot emboss nano-patterns in superionic glass blanks that, in turn, are used for electrochemical imprinting with S4 to reproduce the patterns on Ag substrates. The different steps in this process flow are described along with their role and effectiveness in contributing to a high-fidelity plasmonic image reproduction.
生产金属纳米结构的传统自上而下方法尽管能够生产任意的二维形状,但通常使用真空深亚微米光刻制造技术。这就使得将其用于化学和生物传感基底等一次性设备在经济上难以成立。在此,作者展示了一种仅使用此类技术生产母版的制造途径。这种可重复使用的母版与独特而简便的电化学压印工艺--固态超负离子冲压(S4)--相结合,可用于生产多种复制的金属纳米结构,从而为一次性使用的纳米设备展示了一种经济可行的制造途径。本文将等离子图像复制作为一次性使用设备(如等离子传感器和表面增强拉曼光谱(SERS)基底)的一种易于可视化的代理方法,这些设备需要纳米图案化的金属结构。它展示了通过一组金属结构复制图片的过程,这些金属结构能在局部产生所需的颜色。它使用数字化计算工具、直接写入双光子光刻技术(TPL)和干蚀刻工艺来快速制作硅母版。该母版用于在超离子玻璃坯上热压印纳米图案,然后用 S4 进行电化学压印,在银基板上复制图案。本文介绍了这一工艺流程中的不同步骤,以及它们在高保真等离子图像再现中的作用和效果。
{"title":"Plasmonic image reproduction with solid-state superionic stamping (S4)","authors":"Boqiang Qian,&nbsp;Papia Sultana,&nbsp;Ricardo Toro,&nbsp;Glennys Mensing,&nbsp;Placid Ferreira","doi":"10.1016/j.mfglet.2024.09.073","DOIUrl":"10.1016/j.mfglet.2024.09.073","url":null,"abstract":"<div><div>Traditional top-down approaches for producing metallic nanostructures, despite being capable of producing arbitrary 2-D shapes, often use vacuum-based deep sub-micron lithographic fabrication technologies. This makes their use for single-use devices like chemical and bio-sensing substrates difficult to economically justify. Here, the authors demonstrate a manufacturing pathway that only uses such techniques to produce a master. This reusable master, coupled with a unique and facile electrochemical imprinting process, Solid-State Superionic Stamping (S4), is used to produce several replicated metallic nanostructures, thus demonstrating an economically feasible manufacturing pathway for single-use, nano-enabled devices.</div><div>This paper uses plasmonic image reproduction as an easy-to-visualize proxy for single-use devices such as plasmonic sensors and Surface Enhanced Raman Spectroscopy (SERS) substrates that require nanopatterned metallic structures. It demonstrates a process for replicating a picture by a set of metallic structures that plasmonically produce the desired colors locally. It uses a digitizing computational tool, direct-write Two-Photon Lithography (TPL) and a dry-etch process to rapidly produce a silicon master. This master is used to hot emboss nano-patterns in superionic glass blanks that, in turn, are used for electrochemical imprinting with S4 to reproduce the patterns on Ag substrates. The different steps in this process flow are described along with their role and effectiveness in contributing to a high-fidelity plasmonic image reproduction.</div></div>","PeriodicalId":38186,"journal":{"name":"Manufacturing Letters","volume":"41 ","pages":"Pages 575-580"},"PeriodicalIF":1.9,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Manufacturing Letters
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1