含硼纳米颗粒及其化合物的合成与应用综述

Shreyansh Tatiya, Mohit Pandey, S. Bhattacharya
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引用次数: 7

摘要

纳米材料已经为消费市场上的许多创新产品做出了贡献。不断的努力是为了获得独特的形态和缩小尺寸。因此,新型纳米材料的合成涉及到指数增长的研究。硼及其化合物具有独特的功能和结构特性,广泛应用于从核技术到电子、陶瓷等各个领域。此外,由于它们的无毒性,它们被认为是医疗保健和化妆品行业有吸引力的中间体。大多数关于硼及其化合物的评论都集中在硼化合物的形态和结构上。本文综述了主要的硼化合物的独特性质:碳化硼(B4C)、氮化硼(BN)以及与金属和有机化合物的异质结构。在每个部分中,我们还描述了随后的合成路线以及与之相关的挑战。我们还总结了与硼及其化合物有关的各种形态和形状。然而,近年来对纳米硼颗粒(BNP)的研究主要集中在无毒/绿色和节能的合成路线上。在工业中,纯BNPs的使用和生产非常稀少,通常与硼和其他元素的纳米团簇有关。复杂的结构设计和形成的纳米产品的低纯度使BNP合成具有挑战性。因此,在最后一节中,我们总结了当前研究的挑战和展望,并展望了BNP研究领域的未来前景。
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Nanoparticles containing boron and its compounds—synthesis and applications: A review
Nanomaterials have already contributed to many innovative products in the consumer markets. Constant efforts are directed at attaining unique morphologies and reduction in size. Exponential growth in research is thus involved in the synthesis of the novel nanomaterials. Boron and its compounds with distinct functional and structural properties find extensive usage in a variety of fields ranging from nuclear technology to electronics, ceramics, etc. Also, due to their non-toxicity, they are considered an attractive intermediate in the healthcare and cosmetic industry. The majority of reviews on boron and its compounds are focused on morphologies and the structure of the boron compound obtained. Here, we offer a comprehensive review of the unique properties of the major boron compounds: boron carbide (B4C), boron nitride (BN), and heterostructures with metals and organic compounds. In each section, we also describe the subsequent synthesis routes and the challenges associated with them. We have also summarized the various morphologies and shapes reported to be associated with boron and its compounds. In recent years, however, primary research on boron nanoparticle (BNP) has focused on non-toxic/greener and energy-efficient synthesis routes. The usage and production of pure BNPs in the industry are very scarce and are often associated with nanoclusters of boron and other elements. The intricate structural design and low purity of the nanoproducts formed make BNP synthesis challenging. Thus, in the last section, we summarize the challenges and outlook of the current research with future prospects in the area of BNP research.
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