Tetiana O. Shablii, I. Makarenko, Anastasiia Yu. Bereza, Mariia M. Shuryberko
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冷却系统用水的稳定处理问题与能源工业密切相关。提高水质将减少系统清洗过程中排放的水量。这反过来又减少了对天然水体的污染。本出版物考虑了已经可用的和合成的试剂。用氧乙基二膦酸比较了抗垢剂的效果。已知正在研究的试剂包括苯胺、羧甲基纤维素、柠檬酸和酒石酸以及硝基三甲基膦酸。评价了试剂在不同温度条件下稳定自来水和不同矿化模型溶液的效率。许多试剂的效率被确定为从浓缩溶液中СaSO4沉淀。评估了在较高温度下使用现有试剂和合成试剂进行水稳定的可能性。酒石酸和柠檬酸是反渗透海水淡化浓缩液中非常有效的稳定剂。以亚硫酸钠和甲醛为原料合成了一种新的甲基二磺酸钠沉淀抑制剂;其效率有待评价。
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Оцінка ефективності реагентів для стабілізаційної обробки води циркуляційних систем
The problem of stabilizing treatment of water for cooling systems is very relevant for the energy industry. Increasing water quality will reduce the volume of water discharged during purging of the systems. This, in turn, leads to a reduction in the contamination of natural water bodies. This publication considers both already available and synthesized reagents. Oxyethylidenediphosphonic acid was used to compare the efficiency of antiscalants. The known reagents under study include gipan, carboxymethylcellulose, citric and tartaric acid, and nitriletrimethylphosphonic acid. The efficiency of reagents has been evaluated as for stabilization of tap water and model solutions with different mineralization for different temperature conditions. The efficiency of a number of reagents is determined as for the СaSO4 precipitation from concentrated solutions. The possibility of using available and synthesized reagents for water stabilization at higher temperatures is evaluated. Tartaric and citric acids are quite effective stabilizers in the concentrates of the reverse osmosis seawater desalination. A new inhibitor of precipitation of sodium methyldisulfonate is synthesized on the basis of sodium sulfite and formaldehyde; its efficiency is subject to evaluation.
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