Magnetic Excitations in the Trimeric Compounds A3Cu3(PO4)4(A = Ca, Sr, Pb)

We study the magnetic excitations of the trimeric magnetic compounds A$_3$Cu$_3$(PO$_4$)$_4$ (A = Ca, Sr, Pb). The spectra are analyzed in terms of the Heisenberg model and a generic spin Hamiltonian that accounts for the changes in valence electrons distribution along the bonds among magnetic ions. The analytical results obtained in the framework of both Hamiltonians are compared to each other and to the available experimental measurements. The results based on our model show better agreement with the experimental data than those obtained with the aid of the Heisenberg model. For all trimers, our analysis reveals the existence of one thin energy band referring to the flatness of observed excitation peaks.