ba2o - na2o - k2o三元体系的研究

Rao Guang-hui, Qiao Zhi-yu, L. Jing-Kui
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引用次数: 0

摘要

采用实验测量与理论计算相结合的方法,研究了b2o4 - na2o4 - k2o4三元体系的相图。在对三种亚二元相图进行自洽热力学分析的基础上,采用不对称top方法将优化后的亚二元体系的动力学数据外推到三元体系,并计算了b2o - na2o - k2o - b2o三元相图。计算得到的三元相图与实测的典型垂直剖面相比较,结果令人满意。
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Study on BaB 2 O 4 -Na 2 B 2 O 4 -K 2 B 2 O 4 Ternary System
The phase diagram of B 2 O 4 -Na 2 B 2 O 4 -K 2 B 2 O 4 ternary system has been studied by combination of experimental measurement with theoretical calculation.On the basis of selfconsistent thermodynamic analysis of three sub-binary phase diagrams,the optimized the- rmodynamic data of these sub-binary systems are extrapolated to ternary system by asymmet- rical Toop approach,and the B 2 O 4 -Na 2 B 2 O 4 -K 2 B 2 O 4 ternary phase diagram is calculated. In comparison with a measured typical vertical section,the calculated ternary phase diagram is quite satisfactory.
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