氢氧化钠催化剂配比对改性聚丙烯腈生产生物柴油的影响

R. Hartono
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摘要

生物柴油是一种由植物油脂或动物油脂通过酯交换过程生产的替代柴油燃料。以往的生物柴油研究表明,当植物油原料中游离脂肪酸含量大于2%时,就会发生酯化反应。若游离脂肪酸含量小于2%,则进行酯交换反应。研究以低品位CPO为原料,采用酯化和酯交换工艺制备生物柴油的最佳操作条件。本研究从低品位CPO原料分析开始,在h2so4催化剂下进行酯化反应,在NaOH催化剂下继续进行酯交换反应。研究的固定变量为油体积、1% h2so4催化剂、油与甲醇摩尔比1:6、反应时间、反应温度60℃。研究的固定变量为酯交换过程中NaOH催化剂的比例分别为0.5%、1%和1.5%。分析所得油的游离脂肪酸含量、密度、粘度和含水量。研究结果得到了低品位CPO的理化性质,即含水量0.042%,游离脂肪酸49.03。在氢氧化钠用量为1%的条件下,甲酯收率为60.80%。所得甲酯粘度值为5381 cSt,密度为870 kg/ m3,酸性含量为0.11,含水量为0.028。
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THE EFFECT OF NAOH CATALYST RATIO ON MANUFACTURING BIODISEL FROM OFFGRADE CPO
Biodiesel is a type of alternative diesel fuel derived from plant oils or animal fats produced through the transesterification process. Previous biodiesel studies have stated that esterification reactions are carried out when the content of free fatty acids in vegetable oil raw materials is greater than 2%. If the content of free fatty acids is smaller than 2% then the process of transesterification reaction is carried out. The research aims to find out the optimum operating conditions of biodiesel manufacturing with low grade CPO raw materials using the esterification and transesterification process. The research began with the analysis of low grade CPO raw materials, then carried out the esterification process with the H 2 SO 4 catalyst and continued the transesterification process with NaOH catalyst. Fixed variables in the study were oil volume, 1% of H 2 SO 4 catalyst, mole ratio of oil and methanol 1:6, reaction time and reaction temperature of 60 o C. The fixed variables in the study were NaOH catalyst ratios in the transesterification process of 0.5%, 1% and 1.5%. The oil obtained is analyzed the content of free fatty acids, density, viscosity, and water content. The results of the study obtained the physical and chemical properties of low grade CPO, namely water content 0.042% and free fatty acids 49.03. Optimum operating conditions are obtained with a catalyst ratio of NaOH of 1% with a methyl ester yield of 60.80%. The resulting methyl ester has a viscosity value of 5,381 cSt, a density of 870 kg/m 3 , an acidic content of 0.11 and a water content of 0.028.
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