具有共同中心和不同中心的高维多壳团簇的几何结构

G. Zhizhin
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引用次数: 1

摘要

本文证明了5个壳层中含有561个原子的巨大钯团簇金属骨架的维数为8。一些作者声称在这种情况下钯簇是E8晶格是没有根据的。研究了带有配体和核的多壳金属团簇的内部几何结构。证明了具有共同中心和不同中心的多壳簇具有更高的维数。具有配体和结构单元八面体的簇以不同的金属为核心存在。给出了钴四阴离子团簇的空间图像。证明了它的维数为5。它被认为是具有配体的同元素金属循环。例如,建立了钌和锇的三个核羰基的空间图像。证明了钌和锇的三个核羰基中的配体不像先前假设的那样形成配体多面体。在这种情况下,聚类的构造可以分为两个维数为4的多面体。
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The Geometry of Higher-Dimensional Multi-Shell Clusters With Common Center and Different Centers
In this article, it is shown that the dimension of a metal skeleton of giant palladium cluster, containing 561 atoms in five shells, is 8. The claims of some authors that the palladium cluster in this case is an E8 lattice are groundless. The internal geometry of multi-shell metal clusters with ligands and core was investigated. It is proved that the multi-shell clusters with common center and different centers have a higher dimension. Clusters with ligands and a structural unit octahedron exist with different metals in the core. A spatial image of the cobalt tetra-anion cluster is presented. It is proved that its dimension is 5. It is considered homo-element metal cycles with ligands. For example, a spatial image of the three nuclear carbonyls of ruthenium and osmium it is build. It was proved that the ligands in the three nuclear carbonyls of ruthenium and osmium do not form a ligand polyhedron, as was previously assumed. The construction of cluster in this case can be divided into two polytopes dimension of 4.
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