1,2-丙二醇在毫米波和亚毫米波的实验室光谱学

J. Bossa, M. H. Ordu, H. Muller, F. Lewen, S. Schlemmer
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引用次数: 19

摘要

乙醇二醇是迄今为止在太空中发现的最大的复杂有机分子之一。它存在于不同类型的分子云中。这两个丙二醇异构体是第二大的二醇。因此,它们是在太空中搜索的可行候选者。我们希望提供足够大和准确的1,2-丙二醇的光谱参数集,以便在毫米和更长的亚毫米波长上搜索该分子。我们记录了1,2-丙二醇在38 ~ 400~GHz三个宽频率窗内的旋转光谱。我们对三种最低能量的构象进行了广泛的分配,以获得高达八阶角动量的光谱参数。我们目前的数据将有助于用射电望远镜阵列(如ALMA、NOEMA或EVLA)在中等亚毫米或更长的波长上识别1,2-丙二醇。特别是,用ALMA在源中检测到乙二醇,似乎是有希望的。
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Laboratory spectroscopy of 1,2-propanediol at millimeter and submillimeter wavelengths
Ethanediol is one of the largest complex organic molecules detected in space thus far. It has been found in different types of molecular clouds. The two propanediol isomers are the next larger diols. Hence, they are viable candidates to be searched for in space. We wish to provide sufficiently large and accurate sets of spectroscopic parameters of 1,2-propanediol to facilitate searches for this molecule at millimeter and longer submillimeter wavelengths. We recorded rotational spectra of 1,2-propanediol in three wide frequency windows between 38 and 400~GHz. We made extensive assignments for the three lowest energy conformers to yield spectroscopic parameters up to eighth order of angular momentum. Our present data will be helpful for identifying 1,2-propanediol at moderate submillimeter or longer wavelengths with radio telescope arrays such as ALMA, NOEMA, or EVLA. In particular, its detection with ALMA in sources, in which ethanediol was detected, appears to be promising.
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