以纯种鸡蛋壳为原料,甲醇为溶剂,催化废食用油制备生物柴油

Priska Marisa Pattiasina, I. W. Sutapa, Hellna Tehubijuluw
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引用次数: 0

摘要

以纯种鸡蛋壳为催化剂,甲醇为溶剂,对废食用油进行了合成生物柴油的研究。生物柴油的合成分为酯化反应和酯交换反应两步。以H2SO4为催化剂,甲醇与废食用油的摩尔比为9:1进行酯化反应。以纯种鸡蛋壳中氧化钙为催化剂,甲醇与废食用油的物质比为12:1。CaO催化剂是通过在1000℃下煅烧纯种鸡的蛋壳2小时得到的。用X-RD对煅烧产物进行表征,测定CaO含量。采用1H-NMR、FTIR、GC-MS、ASTM (American Standard Testing of Materials)对所得生物柴油进行表征。生物柴油理论产率为40.298%,实验产率为36.779%。主要成分为硬脂酸甲酯(40.21%)。
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Biodiesel from the waste cooking oil is catalyzed by egg-shell of purebred chicken with methanol as a solvent
The synthesis of biodiesel from the waste cooking oil was carried out using the catalyst from egg shell of purebred chicken with methanol as a solvent. Synthesis the biodiesel was prepared in two steps, there are esterification and transesterification. In esterification was conducted in mol ratio of methanol and waste cooking oil were 9:1, with H2SO4 as a catalyst. Transesterification with mol ratio methanol and waste cooking oil were 12:1, with CaO from egg shell of purebred chicken as a catalyst. CaO catalyst was yielded by calcinations egg shell of purebred chicken on 1000 ⁰C for two hours. Calcination product was characterized with X-RD to determine of CaO. Result of biodiesel was characterized based on 1H-NMR, FTIR, GC-MS, dan ASTM (American Standard Testing of Materials). Yielded of biodiesel theoretically was 40.298% and experiment was 36.779%. Main component that resulted there is methyl stearic (40.21%).
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