天然染料敏化介孔ZnO太阳能电池

Qishuang Wu, Guizhi Wu, M. Cao
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引用次数: 2

摘要

以叶绿素敏化的介孔ZnO(基于FTO)为光阳极,铂板为阴极,组装了天然染料敏化太阳能电池(N-DSSCs)。采用简单的方法从菠菜中提取天然色素叶绿素。研究了叶绿素的吸收光谱和荧光光谱。采用水热法合成了用于N-DSSCs的介孔ZnO (m-ZnO)。通过x射线衍射(XRD)和漫反射对其结构和形貌进行了表征。结果表明,样品的平均孔径为17 nm, m-ZnO为六方纤锌矿结构。在AM 1.5G光照下研究了N-DSSCs的性能。N-DSSCs的Voc约为480mv, Isc约为470μA。通过调整结构可以进一步提高N-DSSCs的性能。
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Natural dye -sensitized mesoporous ZnO solar cell
Natural dye-sensitized solar cells (N-DSSCs) were assembled using chlorophyll sensitized mesoporous ZnO (based on FTO) as the photoanode and platinum plate as the cathode. The natural dyes (chlorophyll) were extracted from spinach by simple procedure. The absorption spectrum and fluorescence spectrum of chlorophyll were studied. Mesoporous ZnO (m-ZnO) applied to the N-DSSCs was synthesized through hydrothermal method. The structures and morphologies were characterized by X-ray Diffraction (XRD) and diffuse reflection. The results indicated that the samples had an average pore size of 17 nm and the m-ZnO was hexagonal wurtzite structure. The performances of the N-DSSCs were investigated under AM 1.5G illumination. The Voc of the N-DSSCs was about 480mv, and the Isc was about 470μA. The performance of the N-DSSCs could be further improved by adjusting its structure.
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