电子吸收光谱法研究钌在氯碱熔体中的行为

PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2019): Proceedings of the VI International Young Researchers’ Conference Pub Date : 2019-12-06 DOI:10.1063/1.5134196

A. Osipenko, V. Volkovich

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引用次数: 1

摘要

在280 ~ 750℃的温度范围内，用电子吸收光谱法研究了钌(III)氯化物在LiCl-KCl-CsCl共晶三元熔体中的行为。确定了稳定的钌(III)氯化物存在的温度范围。确定了熔体中RuCl3浓度下降的机理。在280 ~ 750℃的温度范围内，用电子吸收光谱法研究了钌(III)氯化物在LiCl-KCl-CsCl共晶三元熔体中的行为。确定了稳定的钌(III)氯化物存在的温度范围。确定了熔体中RuCl3浓度下降的机理。

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Study of ruthenium behavior in alkali chloride melts using electronic absorption spectroscopy

The behavior of ruthenium(III) chloro-species was studied in the ternary LiCl–KCl–CsCl eutectic based melts in the temperature range of 280–750 °C using electronic absorption spectroscopy. The temperature range of existence of stable ruthenium(III) chloro-species was determined. The mechanism of RuCl3 concentration decrease in the melt was defined.The behavior of ruthenium(III) chloro-species was studied in the ternary LiCl–KCl–CsCl eutectic based melts in the temperature range of 280–750 °C using electronic absorption spectroscopy. The temperature range of existence of stable ruthenium(III) chloro-species was determined. The mechanism of RuCl3 concentration decrease in the melt was defined.

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PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2019): Proceedings of the VI International Young Researchers’ Conference

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