改进工程氟复合材料技术的方法学途径

S. Avdeychik, E. T. Krut’ko, A. Antonov, V. Struk, A. Lesun
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摘要

讨论了聚四氟乙烯基复合材料的结构和工艺问题。研究表明,由于构件在界面相互作用过程中的惰性表现为填充程度的增加,在传统技术范式的框架内,实现了一种结构悖论。这种矛盾在于氟复合材料的抗拉强度参数随着填充程度的增加而成比例地降低。基于能量概念和组分技术顺应性,提出了通过控制氟复合材料在分子、超分子、相和界面等不同组织层面的结构来消除结构悖论负面影响的技术原则。已经开发出有效的方法,利用含有25-35%(重量)碳纤维的高填充氟复合材料制造产品,其应力-应变特性参数比类似物"Flubon"、"Fluvis"的参数高1.5-2.0倍。
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Methodological approaches to improving the technology of engineering fluorocomposites
Structural and technological aspects of obtaining composite materials based on polytetrafluoroethylene are considered. It is shown that due to the manifestation of the inertness of the components in the processes of interfacial interaction with an increase in the degree of filling, within the framework of the traditional technological paradigm, a structural paradox is realized. This paradox consists in a proportional decrease in the tensile strength parameter of fluorocomposites with an increase in their degree of filling. Based on the concept of energy and technological compliance of components, technological principles for eliminating the negative impact of the structural paradox by controlling the structure of fluorine composites at various levels of organization: molecular, supramolecular, phase and interfacial are proposed. Efficient methods have been developed for manufacturing products from highly filled fluorine composites containing 25–35% (wt.) carbon fiber and having parameters of stress-strain characteristics that are 1.5–2.0 times higher than the parameters of the analogues "Flubon", "Fluvis".
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