以确定相关系数为目的的安培滴定法

Z. Yahshiyeva, M. Yahshiyeva, E. Eshonkulov
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引用次数: 0

摘要

研究了硫代乙酰胺及其金属配合物在不同性质和浓度的缓冲溶液和手机电解质上在铂微盘阳极上的伏安行为。测定了硫乙酰胺的极限阳极电流性质和单分子给电子氧化数,并优化了其溶液测定铂(IV)、钯(II)和金(III)的条件。在所得数据的基础上,说明了将阐述的电化学方法应用于某些实物和工业材料分析的可能性。本文旨在阐述硫乙酰胺溶液测定铂(IV)、钯(II)和金(III)的安培方法,并对所得实验数据的计量值进行了相关系数的确定,其结果可用于不同性质标准样品、矿石、矿物、尾、尾等的分析
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AMPEROMETRIC TITRATION WITH AIM OF DETERMINATION OF THE CORRELATION COEFFICIENTS
Voltamperometric behavior of thioacetamide and its metallocomplexes on the platinum micro disk anode on different by nature and concentrations buffer solutions and phone electrolytes was investigated. Nature of limited anode currents and number of electron donation oxidation of one molecule of thioacetamide were determined and also the conditions of platinum(IV), palladium(II) and gold(III) determination by its solution were optimized. On the base of obtained data the possibility of using of elaborated electrochemical methods to analysis of some real objects and industrial materials was shown. With aim of elaboration of amperometric methods of platinum(IV), palladium(II) and gold(III) determination by thioacetamide solution and metrological value of obtained experimental data the coefficients of correlation were determined, the results of which are useful for analysis of different by nature standards samples, ores, mineral, tails and
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