水分对环氧基材料纳米力学性能的影响

Denvid Lau
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引用次数: 2

摘要

以SU-8为例,成功地进行了环氧基材料的纳米压痕制备。在这样一个小尺度的表征中,我们注意到水分对块体材料的杨氏模量和硬度的变化影响很小,这可能是由于水解的原因。然而,在光学显微镜下,SU-8在水分条件下有明显的变化。尽管水分对大块材料性能的影响很小,但它会对界面断裂能产生不利影响,最终导致粘结体系过早破坏,从而导致耐久性问题,这在各种研究中都有报道。可以设想,SU-8的整体劣化源于它与其他材料结合时的界面。
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Moisture effects on nano-mechanical properties of epoxy-based materials
The nanoindentation of epoxy-based material has been conducted successfully using SU-8 as an example. In such a small scale characterization, it is noticed that moisture has a little effect on the change of bulk material properties in terms of Young's modulus and hardness, probably due to hydrolysis. However, there is an observable change of SU-8 under the optical microscope when the specimens were moisture conditioned. Even though moisture has only a minimal effect on the bulk material properties, it results in a detrimental effect on the interface fracture energy eventually leading to a premature failure of the bonded system, causing a durability problem, which has been reported in various research studies. It is envisioned that the overall deterioration of SU-8 is originated from its interface when bonded with other materials.
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