钕掺杂对Pechini法制备的sr -六铁体磁性和结构性能的影响

M. F. Ramírez-Ayala, T. Pérez-Juache, A. Herrera-González, A. Guerrero
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引用次数: 0

摘要

本文采用溶胶-凝胶法制备了掺钕六铁体锶。掺入不同量的Nd3+改变了阳离子的分布。x ?根据Sr1-xNdxFe12O19的化学表达式,在1100℃下烧结1 h,分析了钕元素对粉末的影响,并分析了制备方法对粉末磁性和结构性能的影响。通过x射线衍射、扫描电镜和透射电镜对样品的晶相、结构和颗粒形貌进行了测定。此外,在室温下使用振动样品磁强计测量磁性能,外加磁场高达20 kOe。此外,磁化强度和矫顽力值受钕含量的影响。结果表明,Pechini溶胶-凝胶法允许Nd3+离子在六铁体结构上的有限溶解度。
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Effect of the neodymium doping on the magnetic and structural properties of the Sr-hexaferrite obtained by the Pechini method
In this work, neodymium (Nd3+) doped strontium hexaferrite was obtained using the sol–gel based Pechini method. The cation distribution was modified by doping with different amounts of Nd3+ ions when 0.0 ? x ? 0.4 according to the chemical expression Sr1-xNdxFe12O19 the powders were sintered at 1100 °C for 1 h. The influence of the neodymium was analyzed, and the magnetic and structural properties have been associated with the fabrication method. The crystalline phases, structure, and particle morphology of the samples were determined by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. In addition, the magnetic properties were measured at room temperature using a vibrating sample magnetometer with an applied field of up to 20 kOe. Moreover, magnetization and coercivity values are influenced by the neodymium content. The results showed that the Pechini sol-gel method allows a limited solubility of the Nd3+ ions on the hexaferrite structure.
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