褐煤中腐植酸和黑藻酸羟甲基衍生物的金属贮存能力评价

I. A. Potapova, E.V. Nielina, N. V. Prokhorova
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引用次数: 0

摘要

腐殖质是最广泛和最活跃的一类天然化合物。一种更节约自然的方法是从固体可燃矿物及其加工过程中的废物中获得腐殖质物质。这些化合物与重金属形成稳定配合物的能力,随着它们的定向化学修饰而增加,已被实验证实。苯酚-甲醛缩合法对初始腐殖质物质进行改性的有效性得到了证实。与初始腐植酸相比,腐植酸和himatomelanic酸与甲醛的相互作用导致对重金属的吸附活性增加。这方面已经在铜离子模型实验中得到了研究和证实。关键词:腐殖质,褐煤,腐殖质和himatomelanic酸,定向化学修饰,羟甲基衍生物,重金属,铜离子,络合物形成
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Metal storage capacity evaluation of humic and himatomelanic acids hydroxymethyl derivatives obtained from brown coal
Humic substances represent the most extensive and reactive class of natural compounds. A more nature-saving way is to obtain humus substances from solid combustible minerals and waste from their processing. The ability of these compounds to form stable complexes with heavy metals, which increases with their directed chemical modification, has been experimentally confirmed. The effectiveness of the phenol-formaldehyde condensation method for the modification of initial humus substances has been confirmed. The interaction of humic and himatomelanic acids with formaldehyde leads to an increase in sorption activity in comparison with the initial humic acids with respect to heavy metals. This aspect has been studied and confirmed in model experiments with copper ions. Key words: humic substances, brown coal, humic and himatomelanic acids, directed chemical modification, hydroxymethyl (methyl) derivatives, heavy metals, copper ions, complex formation.
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