{"title":"射流冷却对苯醌的单重态和三重态n,π *跃迁","authors":"I. Suzuka, M. Sanekata, Mitsuo. Ito, N. Ohta","doi":"10.1155/1994/72592","DOIUrl":null,"url":null,"abstract":"The fluorescence/phosphorescence excitation spectra, the dispersed fluorescence/phosphorescence spectra \nand the sensitized phosphorescence excitation spectrum have been measured for jet-cooled p-benzoquinone. \nThe assignments of vibronic bands in the 1B1g(n-,π∗) ← 1Ag and 1Au(n+,π∗) ← 1Ag transitions \nhave been definitely established. The phosphorescence spectra from vibronic levels of 3Au exhibit a \nfeature of single vibronic level emission. The 3Au ← 1Ag transition was also vibrationally analyzed.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"27 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Singlet And Triplet n,π∗ Transitions of Jet-Cooled p-Benzoquinone\",\"authors\":\"I. Suzuka, M. Sanekata, Mitsuo. Ito, N. Ohta\",\"doi\":\"10.1155/1994/72592\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The fluorescence/phosphorescence excitation spectra, the dispersed fluorescence/phosphorescence spectra \\nand the sensitized phosphorescence excitation spectrum have been measured for jet-cooled p-benzoquinone. \\nThe assignments of vibronic bands in the 1B1g(n-,π∗) ← 1Ag and 1Au(n+,π∗) ← 1Ag transitions \\nhave been definitely established. The phosphorescence spectra from vibronic levels of 3Au exhibit a \\nfeature of single vibronic level emission. The 3Au ← 1Ag transition was also vibrationally analyzed.\",\"PeriodicalId\":296295,\"journal\":{\"name\":\"Laser Chemistry\",\"volume\":\"27 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Laser Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/1994/72592\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Laser Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/1994/72592","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Singlet And Triplet n,π∗ Transitions of Jet-Cooled p-Benzoquinone
The fluorescence/phosphorescence excitation spectra, the dispersed fluorescence/phosphorescence spectra
and the sensitized phosphorescence excitation spectrum have been measured for jet-cooled p-benzoquinone.
The assignments of vibronic bands in the 1B1g(n-,π∗) ← 1Ag and 1Au(n+,π∗) ← 1Ag transitions
have been definitely established. The phosphorescence spectra from vibronic levels of 3Au exhibit a
feature of single vibronic level emission. The 3Au ← 1Ag transition was also vibrationally analyzed.