氧化锌结构依赖性光催化性能研究

I. Sosnin
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引用次数: 0

摘要

本文介绍了氧化锌的结构对其光学、电学和光催化性能的影响。给出了缺陷和晶格对称对光催化活性影响的实例。结果表明,氧空位由于给体的性质可以提高光催化反应的速率,而面化由于氧化锌电导率的各向异性可以改变光催化活性。提出了位错和复杂缺陷对氧化锌光催化性能影响的机理。本研究结果可用于开发基于氧化锌的光催化剂,并用于描述其他半导体的光催化性能。
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Structural-Dependent Photocatalytic Properties of Zinc Oxide
The present paper describes the effect of the structure of zinc oxide on its optical, electrical and photocatalytic properties. Examples of the influence of defects and lattice symmetry on photocatalytic activity are given. It is shown that oxygen vacancies allow to increase the rate of photocatalytic reaction due to donor properties and faceting allows to change the photocatalytic activity due to anisotropy of electric conductivity of zinc oxide. The mechanism of the influence of the dislocations and complex defects on zinc oxide photocatalytic properties is proposed. The present data can be used for development of photocatalysts based on zinc oxide, and for describing the photocatalytic properties of other semiconductors.
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