HEMA - TEOS体系的聚合物-二氧化硅纳米复合材料

G. Khovanets, Y. Medvedevskikh, T. Sezonenko, R. Musiy, V. Zakordonskiy
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引用次数: 1

摘要

采用溶胶-凝胶合成和光引发聚合的方法,在广泛的组成体系变化下制备了2-羟乙基甲基丙烯酸酯(HEMA) -四乙氧基硅烷(TEOS)的有机-无机杂化复合材料(HOIC)。研究了复合材料的光引发聚合动力学随胶凝时间的变化。研究了HOIC组成对其热力学性能和分子结构参数的影响。
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The polymer-silica nanocomposites of the system HEMA - TEOS
Hybrid organic-inorganic composites (HOIC) on the basis of 2-hydroxyethylmethacrylates (HEMA) - tetraethoxysilane (TEOS) were obtained by the methods of sol-gel synthesis and photoinitiated polymerization in a wide range of the composition system changes. The kinetics of photoinitiated polymerization of the obtained composites depending on time of gelation has been studied. The influence of the HOIC composition on their thermomechanical properties and parameters of their molecular structure was investigated.
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