芳香族化合物的氨基烷基化

M. Yuldasheva, K. Turaeva, Tursunali Kholiqov
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引用次数: 0

摘要

系统地研究了苯、甲苯、异构体二甲苯、苯并二氧嘧啶-1,4、间苯二酚的单、二甲基醚、对苯二酚的二甲基醚与甲基和乙基衍生物酰胺和亚胺、乙腈、苯腈和对异构体的酰胺甲基衍生物的反应,并确定了不同因素对其产率和反应方向的影响。提出了芳烃酰胺甲基衍生物、醚、二羟基苯酚的合成及最可能的反应机理。
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Amidoalkylation of aromatic compounds
As the result of systematical investigation of amidomethylation reaction benzene, toluene, isomeric xylenes, benzodioxane-1,4, monoand dimethyl ethers of resorcinole, dimethyl ethers of hydroquinone with methylol and ethylol derivatives amides and imides, acetonitrile, benzonitrile and paraform the amidomethyl derivatives have been obtained and also influence of different factors on their yields and direction of investigated reactions was determined. Synthesis of amidomethyl derivatives of aromatic hydrocarbons, ethers dihydricpenols and most probable reaction mechanism was proposed.
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